How to Solve the Schrödinger Equation for a Finite Potential Well?

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SUMMARY

This discussion focuses on solving the Schrödinger equation for a finite potential well defined by the potential function V(x) = ∞ for x < 0, V(x) = -Vo for 0 < x < a, and V(x) = 0 for x > a, specifically for energy levels E < 0. Participants emphasize the importance of applying boundary conditions at x = 0 and x = a to derive an equation that determines the allowed energy values. The wave function solutions include expressions for the classically forbidden and allowed regions, utilizing constants A and C derived from the differential equation.

PREREQUISITES
  • Understanding of the Schrödinger equation and its applications in quantum mechanics.
  • Familiarity with potential wells and the concept of classically allowed and forbidden regions.
  • Knowledge of boundary conditions and their role in solving differential equations.
  • Ability to manipulate complex numbers and trigonometric functions in wave function solutions.
NEXT STEPS
  • Study the derivation of wave functions for finite potential wells in quantum mechanics.
  • Learn how to apply boundary conditions to solve differential equations in quantum systems.
  • Explore the mathematical techniques for solving the Schrödinger equation in various potential scenarios.
  • Investigate the physical implications of energy quantization in finite potential wells.
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Students and educators in quantum mechanics, particularly those focusing on wave functions and potential wells, as well as researchers interested in the mathematical foundations of quantum theory.

Arbitrationer
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Homework Statement



Hi everyone. This is my first time on her so I hope I make what I'm looking for clear!

The question in the book says,

If V(x) = ∞, x<0 ; -Vo, 0 < x < a ; 0, x > a

Solve the Schrödinger equation for E < 0 inside and outside the well. Apply the boundary conditions at x = 0 and x = a to obtain and equation that determines the allowed values of E.
[/B]

Homework Equations



We just finished going over Finite Potential Wells. Inside the book and in class, we went over the simple case where:

V(x) = 0, -a/2 < x < a/2
V(x) = Vo, elsewhere

I think I get this. We came to the conclusion that, for one case,

ψ(x) = Ceκx for the region to the left (the, what we called in class, "classically forbidden region" (CF)), 2Acos(kx) for the center region (classically allowed (CA)) and Ce-κx for the region to the right (CF)

and for the other case:

ψ(x) = Ceκx (CF), 2iAsin(kx) (CA), -Ce-κx (CF)

Where A and C are just the constants obtained from solving the differential equation once V(x) is plugged into the Schrödinger Equation, and k is different from κ.

[/B]

The Attempt at a Solution



I wish I could say that I made an attempt. I am really confused on where to begin. Any and all help is greatly appreciated!
 
Last edited:
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Arbitrationer said:

Homework Statement



Hi everyone. This is my first time on her so I hope I make what I'm looking for clear!

The question in the book says,

If V(x) = ∞, x<0 ; -Vo, 0 < x < a ; 0, x > a

Solve the Schrödinger equation for E < 0 inside and outside the well. Apply the boundary conditions at x = 0 and x = a to obtain and equation that determines the allowed values of E.
[/B]

Homework Equations



We just finished going over Finite Potential Wells. Inside the book and in class, we went over the simple case where:

V(x) = 0, -a/2 < x < a/2
V(x) = Vo, elsewhere

I think I get this. We came to the conclusion that, for one case,

ψ(x) = Ceκx for the region to the left (the, what we called in class, "classically forbidden region" (CF)), 2Acos(kx) for the center region (classically allowed (CA)) and Ce-κx for the region to the right (CF)

and for the other case:

ψ(x) = Ceκx (CF), 2iAsin(kx) (CA), -Ce-κx (CF)

Where A and C are just the constants obtained from solving the differential equation once V(x) is plugged into the Schrödinger Equation, and k is different from κ.

[/B]

The Attempt at a Solution



I wish I could say that I made an attempt. I am really confused on where to begin. Any and all help is greatly appreciated!
You can start by understanding how the form of the wave function was derived for each region. You're going to take the same basic approach for the current problem.
 
Find k and K by replacing the solutions back into the Schroedinger equation.
The general solution in the potential well is a linear combination of sin(kx) and cos (kx). Apply the boundary conditions to find the relations among the constants. What are the boundary conditions?
 
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