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How would you determine K for the following reaction

  • #1
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How would you determine K for the following reaction:
[tex] HOCl_{aq} + CN^{-} \rightarrow HCN_{aq} + OCN^{-} [/tex]?

You dont do [tex] \frac{1}{K_{a}} [/tex] or [tex] \frac{1}{K_{b}} [/tex]

Thanks
 

Answers and Replies

  • #2
If you mean K as in the equilibrium constant, then I think you would do the following:

[tex]K_c = \frac{[HCN][OCN^{-}]}{[HOCl][CN^{-}]}[/tex], where [] indicate the concentration in moles per liter.

If you're talking about another K, then I can't help you off the top of my head. We just started learning about equilibrium on Monday in AP Chemistry, so you may not want to trust me on this.
 
Last edited:
  • #3
GCT
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Perchloric acid is a strong acid, the reaction will go towards completion.
 
  • #4
Borek
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HOCl is not a strong perchloric acid. HOCl is a pretty weak hypochlorous acid.

There is something wrong with the reaction - where is Cl on the right side?
 
  • #5
I think it should be:

[tex] HOCl_{(aq)} + CN^{-} \rightarrow HCN_{(aq)} + OCl^{-} [/tex]
 
Last edited:
  • #6
Borek
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That was my first idea too, but HOCN does exist (it is cyanic acid) - so perhaps the question was not acid/base related, but redox related - with cyanide being oxidized to cyanate by hypochlorous acid.

No idea what is halfpotential for cyanide/cyanate oxidation.
 

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