Identical particles in a 2D potential well

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Homework Help Overview

The discussion revolves around a two-dimensional potential well problem involving identical particles, specifically bosons and fermions. The original poster seeks assistance in determining energy eigenstates and eigenvalues, as well as constructing wavefunctions for various configurations of particles within the potential well.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning

Approaches and Questions Raised

  • The original poster attempts variable separation to find energy eigenstates and eigenvalues for a particle in a 2D box. They explore the implications of placing identical bosons and fermions in the box, questioning the correctness of their reasoning regarding energy levels and configurations. Participants discuss the representation of wavefunctions and the combination of spatial and spin states for fermions.

Discussion Status

Some participants affirm the original poster's calculations and reasoning, while others provide guidance on how to express the complete wavefunction for fermions. There is an ongoing exploration of how to properly format the combined state of spatial and spin components, with references to lecture notes and textbook examples.

Contextual Notes

The original poster expresses uncertainty about their reasoning in the context of quantum mechanics and the treatment of identical particles, particularly regarding the symmetrization of wavefunctions for fermions and the implications of spin states.

Hannisch
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Homework Statement


So, I'm asking for a bit of help before I confuse myself completely.

The question statement is:

Consider a two-dimensional potentialbox

V(x,y) = 0 if 0 \leq x \leq a, 0 \leq y \leq 2a
and infinity otherwise.

a) Determine the energy eigenstates and energy eigenvalues of a particle in this box. The solutions of the 1D potential well can be considered as known.

b) If we place 3 identical bosons in the box, what will the ground state energy be if we disregard interaction between the bosons.

c) Same as in b), but for 3 identical spin 1/2 fermions.

d) Write down the complete wavefunction (with both spatial and spin parts) for the ground state if two identical fermions with spin 1/2 and without interaction are put in the box.

e) Same as d) but for 3 identical fermions with spin 1/2.

Homework Equations



1D potential well equations:

\psi_n (x) = \sqrt{\frac{2}{a}} {sin(\frac{n \pi x}{a})}

E_n = \frac{n^2 \pi^2 \hbar^2}{2ma^2}


The Attempt at a Solution



Okay, for a) I did a variable separation and ended up with

\psi_{n_{x}n_{y}} (x) = \frac{\sqrt{2}}{a} sin(\frac{n_x \pi x}{a})sin(\frac{n_y \pi y}{2a})

E_{n_{x}n_{y}} = \frac{\pi^2 \hbar^2}{2ma^2}(n_{x}^2 + \frac{n_{y}^2}{4})

Then in b)

Since there are three bosons they can all be in the same state, and the lowest state would be for n_x=n_y=1, so the total energy would be

E_{tot} = 3E_{1,1} = \frac{15 \pi^2 \hbar^2}{8ma^2}

and for c)

Again, the lowest energy will be for n_x=n_y=1, but since only two spin 1/2 fermions can be in that energy at the same time, I'll also have a third particle, which I'm thinking will be in n_x= 1, n_y=2, since this will give me a lower energy than n_x= 2, n_y=1.

So then, the total energy would be:

E_{tot} = 2E_{1,1}+E_{1,2} = \frac{10 \pi^2 \hbar^2}{8ma^2} + \frac{8 \pi^2 \hbar^2}{8ma^2} = \frac{9 \pi^2 \hbar^2}{4ma^2}

And that's where I'm not completely sure if my reasoning is completely correct, and where I want to confirm. I haven't started d) and e) yet, but I want to confirm this first, and I'm going to continue doing the rest with the assumptions I have above until I get a reply or figure something else out.

Thank you for any help that you may provide!
 
Last edited:
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Looks fine!
 
Thank you :D

Well then, I actually need some help with d) as well, it turns out.

Because I know, from c), that the two fermions will be in n_x=n_y=1, so that the wavefunctions will be

\psi_{1,1}^{(1)}(x_1,y_1) = \frac{\sqrt{2}}{a}sin(\frac{\pi x_1}{a})sin(\frac{\pi y_1}{2a})

\psi_{1,1}^{(2)}(x_2,y_2) = \frac{\sqrt{2}}{a}sin(\frac{\pi x_2}{a})sin(\frac{\pi y_2}{2a})

Where the exponent on the psi refers to the particle. And this is because if I solve the Schroedinger equation for two particles I can do a variabel (particle) separation as well, and see that

\psi (x_1,y_1,x_2,y_2) = \psi^{(1)} (x_1,y_1) \psi^{(2)} (x_2,y_2)

So then

\psi (x_1,y_1,x_2,y_2) = \psi_{1,1}^{(1)}(x_1,y_1) \psi_{1,1}^{(2)}(x_2,y_2) = \frac{2}{a^2}sin(\frac{\pi x_1}{a})sin(\frac{\pi y_1}{2a})sin(\frac{\pi x_2}{a})sin(\frac{\pi y_2}{2a})

I also see that this is a symmetric function when exchanging the particles (if this is indeed correct, which I can't honestly say I'm 100% sure about), so I know that they have to be in the singlet spin state.

How on Earth do I write this? Can I just write it as

\psi (x_1,y_1,x_2,y_2)\left| singlet \right\rangle

And can I put in what the singlet state is? I mean, I know it's

\left| singlet \right\rangle = \frac{1}{\sqrt{2}} (\left| \uparrow \downarrow \right\rangle - \left| \downarrow \uparrow \right\rangle)

so can I put this into the equation?
 
Yes, the complete state is a Cartesian product of the spatial state and the spin state. You typically just write them next to each other as you did or perhaps stick a symbol between them indicating it's a Cartesian product. Do you have any examples in your textbook?
 
I honestly can't find any, the closest I came to it was from my lecture notes, where my teacher wrote

|spatial>|spin>

in an example.
 
It's funny. I just checked two of my books, and I can't find an example either. I'd just do what your professor did and write the two pieces next to each other. It's pretty clear what it means.
 

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