Identity Operator for Multiple Particles

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SUMMARY

The identity operator for multiple particles can be expressed as a sum over momentum eigenstates, but normalization becomes complex when dealing with identical particles. The operator A, defined as $$A=\sum\limits_p\sum\limits_q |p,q\rangle\langle p,q|$$ does not yield normalized states without adjustments. To achieve normalization, the operator must be modified, such as by dividing by a constant, yet this approach still leads to non-normalized outcomes. A complete basis for two-particle states must respect the statistics of the particles, resulting in the requirement for symmetric or antisymmetric states.

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  • Understanding of quantum mechanics, particularly the concepts of momentum eigenstates and identity operators.
  • Familiarity with the principles of particle statistics, including Fermi-Dirac and Bose-Einstein statistics.
  • Knowledge of Hilbert spaces and orthonormal bases in quantum mechanics.
  • Experience with the mathematical formalism of quantum state representation, including inner products and completeness relations.
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  • Study the derivation of the identity operator in quantum mechanics for single and multiple particles.
  • Explore the implications of particle statistics on quantum state normalization, focusing on fermions and bosons.
  • Learn about the construction of symmetrized and antisymmetrized states in quantum mechanics.
  • Investigate the completeness relations in Hilbert spaces and their applications in quantum mechanics.
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Hi,

For a particle in a box (so that the momentum spectrum is discrete), we can write the identity operator as a sum over all momentum eigenstates of a projection to that eigenstate: $$I=\displaystyle\sum\limits_{p} |p\rangle\langle p|.$$

I was wondering what the corresponding form of the identity operator would be if we had multiple particles? In particular, a sum over both momenta appears to not lead to normalized states (when the particles are identical): $$A=\displaystyle\sum\limits_p\sum\limits_q |p,q\rangle\langle p,q|.$$ For example, given two possible momentum states for each particle 0 and 1, $$A=\sum\limits_{p=0}^1\sum\limits_{q=0}^1 |p,q\rangle\langle p,q|,$$ we find that $$A|0,1\rangle = |0,1\rangle +|1,0\rangle\langle 1,0|0,1\rangle=|0,1\rangle\pm|1,0\rangle$$ where the + sign is taken if the particles are both bosons and the minus sign if they are both fermions.

This looks like what we're supposed to get up to a normalization constant. I'm trying to figure out exactly how to modify the operator A so that the normalization constant works out. In particular, just dividing A by root 2 to fix this problem, $$A = \dfrac 1{\sqrt 2} \sum\limits_{p=0}^1\sum\limits_{q=0}^1 |p,q\rangle\langle p,q|,$$ we find that $$A|0,0\rangle = \dfrac 1{\sqrt 2}|0,0\rangle$$ which is not normalized.

Any help would be appreciated. Thanks!
 
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I don't know what the most elegant way is to deal with Fermions and Bosons, but one approach is to say that the complete basis does not respect the statistics, and require an additional constraint on physical states that they must be symmetric or antisymmetric.

To make it simple, let's only consider spin degrees of freedom. A complete basis for a single particle is ##|U\rangle## and ##|D\rangle## (spin-up and spin-down along the z-axis, say). A complete basis for a two-particle state is the four states:
  1. ##|U,U\rangle##
  2. ##|U,D\rangle##
  3. ##|D,U\rangle##
  4. ##|D,D\rangle##
The inner product of two states is component-wise:

##\langle X, Y|X, Y\rangle = 1##
##\langle X, Y|X', Y'\rangle = 0## if ##X \neq X'## or ##Y \neq Y'##

So obviously, the identity for two-particle states is:

##I = |U,U\rangle \langle U,U| + |U,D\rangle \langle U,D| + |D,U\rangle \langle D,U| + |D,D\rangle \langle D,D| ##

With this basis, the only two-particle state that respects Fermi antisymmetry is:

##|0\rangle \equiv \frac{1}{\sqrt{2}} (|U,D\rangle - |D,U\rangle)##

And it's clear that ##I |0\rangle = |0\rangle##

In terms of the unsymmetrized basis, ##\langle U, D|D, U\rangle = 0##, not ##-1##.
 
If you have a complete orthonormalized set of vectors ##|u_n \rangle##, then
$$\sum_{n=1}^{\infty} |u_n \rangle \langle u_n|=\mathbb{1}.$$
For your case you have single-particle states ##|p_n \rangle## with ##p_n=2 \pi n \hbar/L##, ##n \in \mathbb{Z}## (for the case of particles in a box with periodic boundary conditions; for rigid boundary conditions this makes no sense at all, because you cannot even define a momentum observable to begin with), forming a complete set of one-particle states.

If you consider two identical particles the Hilbert space is spanned by the totally symmetrized (antisymmetrized) Kronecker-product states,
$$|p_{1j},p_{2k} \rangle=\frac{1}{\sqrt{2}} (|p_{1i} \rangle \otimes |p_{2j} \rangle \pm |p_{2j} \rangle \otimes |p_{1i}).$$
These states are orthonormal, i.e.,
$$\langle p_{1j},p_{2k}|p_{1j'},p_{2k'} \rangle=\delta_{jj'} \delta_{kk'}.$$
The completeness relation then reads
$$\sum_{j,k} |p_{1j},p_{2k} \rangle \langle p_{1j},p_{2k}|=\mathbb{1}.$$
 

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