Heres a pictorial way to show it for the rationals. Start with the positive rationals and start listing them like so
1/1 1/2 1/3 1/4 1/5...
2/1 2/2 2/3 2/4 2/5 ...
3/1 3/2 3/3 3/4 3/5 ...
Now, to count, follow this sequence: 1/2, 1/2, 2/1, 3/1, 2/2, 1/3, 1/4, 2/3,... (I hope you can see what I'm doing). Now, it should be clear that this list is countable. Now, insert the negative rationals just before their positive counterparts, i.e. -1/1, 1/1, -1/2,..., and just put zero at the top left. Now, using the same argument, the full set of Q is countable.
I'm not sure whether this was something like what you were after, but it seems quite intuitive!