Ion Exchange Between Salts in a Solution

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Discussion Overview

The discussion centers on the ion exchange between alkaline Earth metal-halide salts in a solution, specifically examining the formation of new salts upon boiling off water and the factors influencing this process, including solubility and enthalpy of formation. The scope includes theoretical and conceptual aspects of chemistry.

Discussion Character

  • Exploratory, Conceptual clarification, Debate/contested

Main Points Raised

  • One participant questions whether boiling off water from a solution of potassium iodide and sodium chloride will lead to the formation of potassium chloride and sodium iodide, and whether the most and least electronegative ions will seek each other out.
  • Another participant suggests that the outcome will depend on the solubilities of the salts, indicating that less soluble salts will crystallize first.
  • A later reply inquires about the role of enthalpies of formation in determining the resulting salts and whether precipitation reactions could occur without removing water.

Areas of Agreement / Disagreement

Participants express differing views on the outcomes of the ion exchange process, with no consensus reached on the specifics of salt formation or the influence of enthalpy and solubility.

Contextual Notes

The discussion does not resolve the assumptions regarding solubility and enthalpy effects, and the implications of these factors on the final composition of salts remain unclear.

APeterson
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If you have two alkaline Earth metal-halide salts in a solution (for example potassium iodide and sodium chloride), when you boil off the water will you find that new salts (In this case potassium chloride and sodium iodide) have formed? Will the most electronegative and least electronegative ions seek each other out? Will you end up with only two salts at the end, assuming you had equal proportions of the salts at the beginning, or will you end up with various similar concentrations of 4 salts?
 
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What will happen depends mostly on solubilities - less soluble salts will start to crystallize first, followed by the less soluble ones.

http://en.wikipedia.org/wiki/Fractional_crystallization_(chemistry )
 
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Thanks.
 
Also, do enthalpies of formation have any meaningful effect on which salts result? Could you theoretically have a precipitation reaction if you don't remove the water?
 

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