Irreversible reaction in a battery

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SUMMARY

The discussion centers on the nature of chemical reactions in batteries, specifically the distinction between reversible and irreversible reactions. In an ideal battery, the oxidation-reduction reaction Zn + Cu2+ = Zn2+ + Cu occurs at equilibrium, allowing for reversibility. However, real batteries experience resistivity, leading to irreversible reactions. Participants clarify that during irreversible reactions, the reaction does not proceed in both directions but rather resembles a one-way combustion reaction.

PREREQUISITES
  • Understanding of oxidation-reduction reactions
  • Familiarity with battery chemistry
  • Knowledge of chemical equilibrium concepts
  • Basic principles of resistivity in materials
NEXT STEPS
  • Research the principles of electrochemistry in batteries
  • Study the effects of resistivity on chemical reactions
  • Learn about the differences between reversible and irreversible reactions
  • Explore the concept of chemical equilibrium in detail
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Students of chemistry, battery engineers, and anyone interested in the electrochemical processes within batteries.

tonyjk
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Hello,

Inside an ideal battery, the chemical reaction is reversible (at equilibrium), thus the oxydation-reduction reaction Zn + Cu2+ = Zn2+ + Cu is happening in both ways at the same rate right?

Now, for a real battery, there's resistivity inside it due to many factors, thus the chemical reaction is irreversible. My question is, during the irreversible reaction, is the reaction happening in both ways but at different rate due to resistivity inside the battery or it is just like the combustion reaction happening in one way?

Thanks
 
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Please elaborate. "Reversible" and "at equilibrium" are two different things, I don't see why you are mixing them.
 
Borek said:
Please elaborate. "Reversible" and "at equilibrium" are two different things, I don't see why you are mixing them.
Sorry but chemistry is not my domain. I thought that a chemical reaction at equilibrium thus it is a reversible reaction.
 

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