Is the Exchange-Correlation Hole Truly Positive in a Homogeneous Electron Gas?

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SUMMARY

The exchange-correlation hole in a homogeneous electron gas is considered "positive" due to the jellium model, which posits a uniform positive background charge. When electrons are removed from this medium, the deficit of negative charge results in a net positive charge, thus defining the exchange-correlation hole as positive. This concept is crucial for understanding electron interactions in condensed matter physics.

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  • Concept of exchange-correlation in density functional theory
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saray1360
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Hi,

Why do we say that the exchange correlation hole is "positive" in a medium like a homogeneous electron gas, while all the particles are electrons with negative charge.

Is only the deficit of the electron mean positive charge?

Regards,
 
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Basically, yes. You can think of it as in the jellium model, where there is a uniform positive background charge, and a removal of electron charge by the exchange-correlation hole leaves behind just the positive background charge, making the xc hole positive.
 

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