Kinetic Theory of Gases: Effusion and Collisions

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Homework Help Overview

The discussion revolves around the Kinetic Theory of Gases, specifically focusing on the concepts of effusion and molecular collisions as presented in a lecture note. The original poster expresses concern about potential inconsistencies in the notation and angles used in the document, particularly regarding the angles \upsilon and \theta in relation to a parallelepiped diagram.

Discussion Character

  • Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • The original poster questions the use of different angles in the context of the parallelepiped and whether they should all refer to \upsilon. Another participant suggests that the angle in question might actually be \theta, prompting a clarification on the notation.

Discussion Status

The discussion is ongoing, with participants exploring the potential for a typo or error in the lecture notes. Some guidance has been offered regarding the angles, but there is still uncertainty about the correct interpretation of the mathematical expressions related to flux and distribution.

Contextual Notes

Participants are navigating through the complexities of the notation used in the lecture notes, with specific attention to the mathematical expressions involving exponential factors. There is mention of a legitimate error identified by one participant regarding the missing factor in the exponent, which adds to the complexity of the discussion.

xatu
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Question:

In the following link I'm concerned with only pages 1 and 2. I'm wondering if there is a typo or an error of some kind. I feel like there is some inconsistency to what the author refers to as \upsilon, \theta, and \phi. The only angle shown in the diagram is \upsilon, which is the angle the constructed parallelepiped makes with the surface normal.

For instance, the volume of the parallelepiped involves \upsilon and the # of molecules crossing through dA in time dt involves \theta, but then the flux again involves \upsilon. Shouldn't all of those quantities involve only \upsilon?

http://ocw.mit.edu/courses/chemistr...y-ii-spring-2008/lecture-notes/29_562ln08.pdf

Hopefully I am wrong. Thanks in advance for any help guys.
 
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xatu said:
The only angle shown in the diagram is \upsilon, which is the angle the constructed parallelepiped makes with the surface normal.
It's not \upsilon, it's a somewhat stylised \theta. Does that resolve it?
 
Wow, I feel horrendously stupid. Sorry for wasting your time, haruspex.
 
However, I did stumble across a legitimate error. The distribution, as well as the average flux, should contain e^{\frac{-mv^{2}}{2kT}}. What is shown is e^{\frac{-mv^{2}}{kT}} - missing the factor of 2 in the dominator of fractional exponent. However, the correct answer is shown for the result of the integral. Still should have that factor of 2 though.
 
xatu said:
Wow, I feel horrendously stupid. Sorry for wasting your time, haruspex.
If it allows you to progress, my time was not wasted.:cool:
 

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