When comparing the hazards of 0.1 M HCl and 0.1 M NaOH to the eyes, NaOH is considered more dangerous. While both substances are toxic, NaOH is more corrosive and can cause significant damage before pain is felt, making it particularly hazardous. In contrast, HCl causes immediate irritation upon contact. Proper handling and safety measures are essential, including good ventilation and thorough hand washing to prevent accidental exposure. Rinsing with water is less effective for NaOH, which increases the risk of severe eye damage.