Mass Spectrometry Homework: Determining Atomic Mass

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SUMMARY

The discussion centers on determining the atomic mass of a rarer carbon isotope using mass spectrometry principles. The most abundant isotope has an atomic mass of 12.0000 u, and the radii of their paths in the mass spectrometer are 9.00 cm for the abundant isotope and 9.36 cm for the rarer one. The initial calculation suggested an atomic mass of 12.48 u for the rarer isotope, which was later identified as incorrect due to the misunderstanding that both isotopes have the same velocity after being accelerated through the same potential difference.

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  • Understanding of mass spectrometry principles
  • Familiarity with isotopes and atomic mass concepts
  • Knowledge of the equation r = mv^2 / qvB
  • Basic physics of charged particles in magnetic fields
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  • Review the principles of mass spectrometry and how isotopes are separated
  • Study the effects of potential difference on ion velocities in mass spectrometry
  • Learn about the calculation of atomic masses from mass spectrometer data
  • Explore the concept of isotopic abundance and its impact on average atomic mass
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Homework Statement



Natural carbon consists of two different isotopes (excluding 14C, which is present in only trace amounts). The isotopes have different masses, which is due to different numbers of neutrons in the nucleus; however, the number of protons in the same, and subsequently the chemical properties are the same. The most abundant isotope has an atomic mass of 12.0000 u. When natural carbon is placed in a mass spectrometer, two lines are formed on the photographic plate. The lines show that the more abundant isotope moved in a circle of radius 9.00 cm, while the rarer isotope moved in a circle of radius 9.36 cm. What is the atomic mass of the rarer isotope? (The ions are accelerated through the same potential difference before entering the magnetic field.)

Homework Equations



r = mv^2 / qvB

The Attempt at a Solution



Charges, velocities, and magnetic fields are the same. Set up ratio:

radius abundant / radius rarer = mass abundant / mass rarer

9 cm / 9.36 cm = 12 u / x

x = 12.48 u

This answer shows as incorrect. Any thoughts? Thanks.
 
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azhoops said:

Homework Statement


(The ions are accelerated through the same potential difference before entering the magnetic field.)

If they are accelerated through the same potential difference they don't have the same velocity.
 
Thanks! I got it.
 

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