Methods for Quantitating Impurity

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Homework Statement


Which of the following allows you to quantitatively determine the composition of a crude product after synthesis? Explain.
a. NMR
b. melting point
c. TLC


Homework Equations


none


The Attempt at a Solution


I know that TLC is used for determining whether an impurity is present or not, so I don't think it can determine how much of an impurity there is. I'm not sure about NMR and melting point though. Please help?
 
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What quantitative methods do you know? How do they work?

What is the integration curve in NMR?