What does 300 cm⁻¹ mean?
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LeonhardEuler
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It means the same thing as [itex]\frac{1}{cm}[/itex]. For instance, [itex]3m s^{-1}[/itex] means the same thing as [itex]3\frac{m}{s}[/itex]
LeonhardEuler
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That can't be right for a distance. Can you give the exact sentence?
Mentor
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Sure, here it is.
"Since both rotational and vibrational motions are simultaneously occurring in the diatomic, the energy level scheme for two adjacent vibration levels (spaced, say, 3000 cm-1 apart) where ca. 10 cm-1 in the two states, would be as shown in Fig. 1."
From the article here: http://www.chem.ufl.edu/~itl/4411L_f00/hcl/hcl_il.html
Edit: Copy and Pasting didn't keep the exponents like they were in the article, as they now look like I typed it out.
"Since both rotational and vibrational motions are simultaneously occurring in the diatomic, the energy level scheme for two adjacent vibration levels (spaced, say, 3000 cm-1 apart) where ca. 10 cm-1 in the two states, would be as shown in Fig. 1."
From the article here: http://www.chem.ufl.edu/~itl/4411L_f00/hcl/hcl_il.html
Edit: Copy and Pasting didn't keep the exponents like they were in the article, as they now look like I typed it out.
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LeonhardEuler
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Ok, it's not a measurement of the physical distance between atoms, it's a measure of the difference in frequency between the radiation emitted by two modes of vibration of the pair of atoms. This measurement is called the "wavenumber":
http://en.wikipedia.org/wiki/Wavenumber
The higher the wavenumber, the higher the energy of the vibration.
http://en.wikipedia.org/wiki/Wavenumber
The higher the wavenumber, the higher the energy of the vibration.
Homework Helper
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Drakkith said:Sure, here it is.
"Since both rotational and vibrational motions are simultaneously occurring in the diatomic, the energy level scheme for two adjacent vibration levels (spaced, say, 3000 cm-1 apart) where ca. 10 cm-1 in the two states, would be as shown in Fig. 1."
From the article here: http://www.chem.ufl.edu/~itl/4411L_f00/hcl/hcl_il.html
Edit: Copy and Pasting didn't keep the exponents like they were in the article, as they now look like I typed it out.
http://en.wikipedia.org/wiki/Wavenumber
It's used for the wavenumber, which is proportional to the reciprocal of the wavelength (which is measured in cm). Why wavenumbers are important isn't a question I could answer. I forgot a lot of physics. =(
Euler beat me!
Last edited by a moderator:
Mentor
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gb7nash said:http://en.wikipedia.org/wiki/Wavenumber
It's used for the wavenumber, which is proportional to the reciprocal of the wavelength (which is measured in cm). Why wavenumbers are important isn't a question I could answer. I forgot a lot of physics. =(
Euler beat me!
Thanks to you too nash. =)