NH3 Molecular Geometry: Understanding Electron Pair Geometry and Lone Pairs

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SUMMARY

The molecular geometry of NH3 (ammonia) is trigonal pyramidal, not trigonal planar, due to the presence of one lone pair among four electron pairs. The electron pair geometry is tetrahedral, which minimizes electron repulsion by positioning the electron pairs as far apart as possible. This principle also applies to H2O (water), where the molecular geometry is angular despite its tetrahedral electron pair geometry. Understanding these geometries is essential for predicting molecular shapes based on VSEPR theory.

PREREQUISITES
  • VSEPR theory (Valence Shell Electron Pair Repulsion theory)
  • Understanding of molecular geometry and electron pair geometry
  • Familiarity with tetrahedral and trigonal pyramidal shapes
  • Basic knowledge of lone pairs and their effects on molecular shape
NEXT STEPS
  • Research VSEPR theory in detail to understand molecular shape predictions
  • Study the electron pair geometries of other compounds like H2O and CH4
  • Explore the impact of lone pairs on molecular geometry
  • Examine examples of trigonal pyramidal and angular geometries in various molecules
USEFUL FOR

Chemistry students, educators, and anyone interested in molecular geometry and the principles of VSEPR theory will benefit from this discussion.

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Homework Statement


I'm trying to figure out the electron pair geometry of NH3. I know that its molecular geometry is a trigonal plane, and it has 4 electron pairs total, including one lone pair.

Homework Equations


N/A just nh3 molecular geometry

The Attempt at a Solution


Should the e- pair geometry be a tetrahedron? I'm a little confused.
 
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I just came across another situation that confuses me. How do you rationalize the molecular geometries? For e- pair geometries, my understanding is that your goal is to minimize electron repulsion, therefore you use the geometry that will place the pairs as far away as possible from one another. What is the rule of thumb for molecular geometries, if there is one?

For example, I am stuck on H2O. I completely understand why the e- pair geometry is a tetrahedron, but I have absolutely no idea how the molecular geometry comes out to be angular. The same goes for any of the compounds with pyramidal geometries.
 
The shape of NH3 is not trigonal planar but trigonal pyramidal. Take a look at the images at wikipedia
http://en.wikipedia.org/wiki/Nh3

You know that with four electron pairs, they move as far away from each other as possible and form the vertices, or corners, of a tetrahedron. With H2O, there are two hydrogens, each at one of the corners of the tetrahedron; they are not in a straight line but rather at an angle
 

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