Noble gases don't react chemically with other substances

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Discussion Overview

The discussion revolves around the reactivity of noble gases, specifically questioning the accuracy of the statement that "noble gases don't react chemically with other substances." Participants explore the conditions under which noble gases may form compounds and the implications of these reactions.

Discussion Character

  • Debate/contested
  • Conceptual clarification
  • Technical explanation

Main Points Raised

  • Some participants assert that the statement about noble gases is ordinarily correct, but under extraordinary conditions, compounds can be formed, albeit with potential instability.
  • Compounds such as XeF2 are mentioned as commercially available and used in applications like microelectronics, suggesting that noble gas compounds are not merely lab curiosities.
  • There is a question about whether limiting reactions to noble gases implies they react with each other, which some participants suggest could be incorrect.
  • One participant expresses frustration that the notion of noble gases being unreactive is still taught, arguing that it has not been true for 55 years and providing anecdotal evidence of purchasing XeF2.
  • Another participant notes that while noble gases are generally inert, they can react under special circumstances, and compares the ionization energy of xenon to that of oxygen to illustrate its reactivity.

Areas of Agreement / Disagreement

Participants generally agree that noble gases are mostly unreactive under normal conditions but disagree on the implications of this statement and the extent of their reactivity under specific conditions. Multiple competing views remain regarding the teaching of noble gas reactivity.

Contextual Notes

There are unresolved questions regarding the stability of noble gas compounds and the conditions necessary for their formation. The discussion reflects a range of assumptions about the definitions of reactivity and the context in which noble gases are considered.

mech-eng
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I would like to ask about a question concerning noble gases. "Nobel gases don't react chemically with other substances."

Is this statement about nobles gases completely correct or partially correct?

Thank you

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Ordinarily correct. In extraordinary conditions, compounds can be made, maybe not very stable.
 
symbolipoint said:
Ordinarily correct. In extraordinary conditions, compounds can be made, maybe not very stable.
Compounds like XeF2 are available commercially and are used as an etching agent in microelectronics. So I wouldn't regard noble gas compounds as a lab curiosity.
 
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symbolipoint said:
Ordinarily correct. In extraordinary conditions, compounds can be made, maybe not very stable.

If we limit the reaction with other substances, does this not mean that they react with each other, and which would be wrong?

Thank you.
 
DrDu said:
Compounds like XeF2 are available commercially and are used as an etching agent in microelectronics. So I wouldn't regard noble gas compounds as a lab curiosity.

So being commercially available, does that mean it is stable, or stable enough for some known storage period?

mech-eng said:
If we limit the reaction with other substances, does this not mean that they react with each other, and which would be wrong?

Thank you.
See what Dr.Du said.
 
mech-eng said:
If we limit the reaction with other substances, does this not mean that they react with each other, and which would be wrong?

Thank you.
I think that even compounds with Xe-Xe covalent bonds have been synthesised.
 
mech-eng said:
I would like to ask about a question concerning noble gases. "Nobel gases don't react chemically with other substances."

Why is this still being taught? It hasn't been true for 55 years. You can buy XeF2 out of a catalog - I just confirmed if I gave them my credit card number, I could have some on my desk by tomorrow. It's only about 3x as expensive as gold, by weight.
 
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Vanadium 50 said:
Why is this still being taught? It hasn't been true for 55 years. You can buy XeF2 out of a catalog - I just confirmed if I gave them my credit card number, I could have some on my desk by tomorrow. It's only about 3x as expensive as gold, by weight.
I generally see it taught as "noble gases are inert under most conditions and only react in special circumstances," or some such qualification. But saying they're unreactive isn't a terrible approximation. Xenon's first ionization energy is comparable to that of O2, which means that oxidizing xenon is about as difficult as oxidizing oxygen. (In fact this was exactly how Neil Bartlett reasoned that xenon might be reactive--his experience with oxygenyl compounds of platinum hexafluoride. (sub-gripe: it's completely beyond me why he never won a Nobel Prize)).
 
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