One question on average thermal velocity of free electron in metals

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SUMMARY

The average thermal velocity of free electrons in metals is zero in the absence of an electric field, as established in Classical Free Electron Theory. This principle indicates that, at thermal equilibrium, electrons do not exhibit a net current, preventing charge accumulation in any part of the metal. Such accumulation would violate thermodynamic laws and disrupt the equilibrium state. Therefore, the thermal velocity distribution of electrons remains balanced, ensuring no directional movement on average.

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  • Understanding of Classical Free Electron Theory
  • Basic principles of thermodynamics
  • Knowledge of thermal equilibrium concepts
  • Familiarity with electron behavior in solid-state physics
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ray.deng83
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Hi, I'm a student learning Solid State Physics and in a chapter of Classical Free Electron Theory of Metals in the textbook, it mentions "Since in the absence of a (electric) field there can be no net current, it is clear that the average thermal velocity over the equilibrium (thermal velocity) distribution must be zero." I don't quite understand why it should be zero. Can someone explain this to me?
 
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Because if it was not zero charges could accumulate in some part of the metal, which would violate the laws of thermodynamics (and it would also not be a equilibrium state anymore).

All that statement means is that electrons in a thermal equilibrium are -on average- not going anywhere.
 

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