Particle in Two Boxes: Impact of Dividing Barrier on Energy State

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SUMMARY

The discussion centers on the quantum mechanics of a particle in a 1-dimensional box and the effects of dividing the box with an impenetrable barrier. Initially, the energy of the particle in its lowest state is given by E = h^2/(8*m*d^2). When the box is divided into two equal sections, A and B, each with length d/2, the minimum energy state for the particle in either box becomes E = 4*h^2/(8*m*d^2), indicating an increase in energy due to confinement. This phenomenon raises questions about energy conservation, as the insertion of the barrier requires energy input, which is transferred to the particle. The discussion also references Gibbs' Paradox in relation to entropy, suggesting a deeper connection between confinement and energy states.

PREREQUISITES
  • Quantum mechanics fundamentals
  • Understanding of energy quantization in confined systems
  • Familiarity with the concept of time-dependent potentials
  • Knowledge of Gibbs' Paradox and its implications on entropy
NEXT STEPS
  • Explore the implications of time-dependent potentials in quantum mechanics
  • Study the derivation and applications of the energy formula E = h^2*n^2/(8*m*L^2)
  • Investigate Gibbs' Paradox and its relevance to statistical mechanics
  • Examine the effects of confinement on particle behavior in quantum systems
USEFUL FOR

Students and professionals in physics, particularly those focusing on quantum mechanics, energy states, and statistical mechanics. This discussion is beneficial for anyone interested in the implications of confinement on particle energy and entropy.

chrisphd
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Suppose we have a particle in a 1-dimensional box, such that the particle is in its lowest energy state. The energy of a particle in a 1-dimensional box is E = h^2*n^2/(8*m*L^2). Therefore, if the particle is in its lowest energy level, n = 1, and the box has a length of d, then E = h^2/(8*m*d^2). Now suppose we divide the box into two boxes, A and B, using an impenetratable barrier so that each new box has a length of d/2. Now, if the particle is found to be in box A, the minimum energy it can have is n = 1, where E = h^2*n^2/(8*m*L^2) and therefore, E= h^2/(8*m*(d/2)^2) = 4*h^2/(8*m*d^2). This is the same for the particle being found in box B by symmetry. How is it possible that the energy has increased by simply adding a dividing barrier.
 
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The process of insertion of the barrier would require energy. That energy would be transmitted to the particle. The whole process can be simulated by a time-dependent potential. It is known that a time-dependent potential corresponds to a non-conserved energy due to an external energy source.
 
To Me

Well Gentleman To Me The Energy Of Particle Is Decreased On Applying Barrier,bcoz We Have Restricted Particle To Finite Area.if We Further Introduce Separation,then Again Energy Is Decreased.so What We Are Doing,is Just Limiting Its Range Of Freeness.
Have You Studied Gibb's Paradox,it Also Tell The Same Thing But Regarding Entropy.
 

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