Calc % Ag in Alloy: 0.6353g Ag2/ 0.5000g alloy x 100% = 12.9%

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SUMMARY

The discussion focuses on calculating the percentage of silver (Ag) in a copper-silver alloy weighing 0.5000 grams. The process involves dissolving the alloy in HNO3 and precipitating the silver and copper sulfides using H2S. The final calculation reveals that the percentage of silver in the alloy is 12.9%, derived from the mass of silver sulfide (Ag2S) produced, which weighs 0.7300 grams. The calculations utilize stoichiometric relationships and molar mass conversions to arrive at the final percentage.

PREREQUISITES
  • Understanding of stoichiometry and chemical equations
  • Familiarity with molar mass calculations
  • Knowledge of precipitation reactions in inorganic chemistry
  • Basic skills in algebra for solving equations
NEXT STEPS
  • Study the principles of stoichiometry in chemical reactions
  • Learn about the molar mass of common compounds, specifically silver sulfide (Ag2S)
  • Explore precipitation reactions and their applications in analytical chemistry
  • Practice solving problems involving percentage composition in alloys
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Chemistry students, educators, and professionals involved in materials science or metallurgy who are interested in quantitative analysis of metal alloys.

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Homework Statement


An alloy of copper and silver weighing 0.5000 grams is dissolved in HNO3 and treated with H2S to precipitate both CuS and Ag2S. It is found that the solid sulphides weigh 0.7300 grams. Calculate the percentage of Ag in the alloy. (12.9 %)

2Ag+(aq) + H2S(aq)→ Ag2S(s) + 2H+(aq)
Cu+2(aq) + H2S(aq)→ CuS(s) + 2H+(aq)

Homework Equations


mass of Ag/mass of alloy = % of Ag

The Attempt at a Solution


I'm not too sure how to start this question…

So far, I have

0.7300 g Ag2S x 1 mol / 215.74 g Ag2
= 2.945 x 10-3 mol Ag2S

2.945 x 10-3 mol Ag2S x 215.74 g Ag2/ 1 mol Ag2S
= 0.6353 g Ag2I'm not sure if I'm on the right track here?
 
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You have a system of two equations in two unknowns.
 

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