Polarizability of a single hydrogen atom

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SUMMARY

The discussion centers on the polarizability of a single hydrogen atom, specifically addressing the solution of the Schrödinger equation. The user derived the wave function psi(x) = c1*cos(kx) + c2*sin(kx), where k = sqrt(2Em)/hbar. The main challenge presented is the selection of appropriate boundary conditions for the problem. Additionally, there is a suggestion to consider perturbation theory in conjunction with the Stark effect to analyze the atom's response to an external electric field.

PREREQUISITES
  • Understanding of the Schrödinger equation and its solutions
  • Familiarity with quantum mechanics concepts, particularly wave functions
  • Knowledge of boundary conditions in quantum systems
  • Basic principles of perturbation theory and the Stark effect
NEXT STEPS
  • Study the application of boundary conditions in quantum mechanics
  • Explore perturbation theory in detail, focusing on its application to atomic systems
  • Research the Stark effect and its implications for atomic polarizability
  • Examine examples of polarizability calculations for hydrogen and other atoms
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Students and researchers in quantum mechanics, particularly those focusing on atomic physics and the behavior of hydrogen atoms under external fields.

Cranky
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Homework Statement



the problem text is attached

Homework Equations





The Attempt at a Solution



I have solved Schrödingen equation, while getting
psi(x)=c1*cos(kx)+c2*sin(kx), where k=sqrt(2Em)/hbar
I cannot understand which boundary conditions I schould use.
 

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Bump; is the approach to use perturbation theory with the Stark effect?
 

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