Possible Dipole Transitions from 5p to 4s in Potassium

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SUMMARY

The discussion focuses on the possible dipole transitions from the 5p to the 4s state in potassium, specifically identifying valid pathways for electron relaxation. The confirmed transitions include 5p → 5s → 4p → 4s and 5p → 4s. The incorrect transition 5p → 3d is noted due to the requirement that the orbital angular momentum quantum number (l) must change by ±1, which disqualifies this pathway.

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Max Eilerson
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An electron is excited to the 5p state in potassium, list all the possible dipole transitiosn that can occur as the electron relaxes to the 4s level. (Ignoring fine structure effects)

I've got

5p -> 5s -> 4p -> 4s
5p -> 4s

I'm not sure whether to also include

5p - > 3d -> 5s
3d -> 4p
3d -> 4s
 
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All correct except the 5p -> 3d, as l changes by 2. I knew that transitions needed change in l =+- 1 but thought the 5p and 3d states were interchangeable?
 

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