Potato battery, how does it work?

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SUMMARY

The potato battery operates through electrochemical reactions facilitated by the phosphoric acid (H3PO4) present in the potato. The zinc nail acts as the anode, oxidizing to Zn(+2) while the copper coin serves as the cathode, reducing Cu(+2) to Cu(s). The standard electrode potentials indicate that zinc has a higher tendency to oxidize compared to copper, enabling the flow of electrons. While the potato battery can generate a small voltage, it is insufficient to power devices like a light bulb, but it can produce enough energy to light up a pickle as demonstrated in related experiments.

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christian0710
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Hi just made a potato battery, using a cupper coin and zink nails (not connected in any way, just pit in a nail and 3 inches appart a penny), I was just wondering what is the chemistry/physics theory here?

Potatoes contain phosphoric acid
H3PO4

Is it the acid in potatoes that oxidize the 2 metals? or id it the standard electrode potential?

Electrode potential for Zn
Zn(+2) + 2e ---> Zn(s) = -0,76 V (so it want's to be oxidized and should reduce Cu (+2) to Cu (s) because Cupper has a positive electrode potential.

But does the acid oxidize both metals in the first place?
 
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Hmmm... can a potato battery produce enough "juice" to light up a pickle?

pickle.jpg


http://hyperphysics.phy-astr.gsu.edu/hbase/electric/pickle.html
 
Using a potato is just one of infinity of choices. Any electrolyte should work given it does not pasivate the surface of the metals.
 

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