Predict whether the following is neutral, basic, or acidic and the pH

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NH4Br is identified as an acidic salt due to the presence of the NH4+ ion, which acts as an acid in solution. The dissociation of NH4+ leads to the formation of H3O+, and the pH can be calculated using the provided Ka value of 5.52 x 10-10. The calculation involves setting up an equilibrium expression based on the dissociation reaction and solving for the concentration of H3O+. The confusion arises from the calculation steps, but the final pH of 4.92 is confirmed as correct. The pH is primarily influenced by the dissociation of NH4+, not by Br-, which is neutral.
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1. 0.250 M of NH4Br



2. Ka for NH4 = 5.52 x 10-10 and Kb for NH3 = 1.81 x 10-5


3. So I broke the salt down into its constituents and considering Br is neutral and NH4 is an acid, NH4Br is acidic. I am just confused with how to calculate the pH. I thought that I should do this...NH4 + H2O → NH3 + H3)
At equilibrium, NH4 = (0.1 M -x) NH3 = +x and H3O = +x
Then the Ka value 5.52 x 10-10 = x2/(0.25-x) and then solve for x

The x value = the concentration of H3) and then I take the -log(H3O).

I keep getting the wrong answer, so I am just wondering if the steps I have taken are correct? Also, the pH = 4.92
 
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I actually just the got answer. But if someone could reply in regards to why the pH of the salt solution of o,25 M NH4Br = the dissociation of NH4 to give H3O?
 
HBr is a strong acid. As such, the Br will not react with H2O to form HBr. Thus, the pH is completely dependent on the Ka of NH4, which determines the concentration of H3O+ in solution.
 

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