Quantum Mechanics Infinite Potential Well -- Check Answers please

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SUMMARY

The discussion focuses on the quantum mechanics concept of a particle in a one-dimensional infinite potential well, specifically analyzing the wave function and its expansion in terms of eigenfunctions. The wave function is defined as ##\Psi (x, t=0) = \sqrt{\frac{4}{a}}## for ##0 \leq x \leq a/4##, and the coefficients for the expansion are calculated as ##c_{n} = \frac{8-4\sqrt{2}}{n\pi}## for odd n and ##c_{n} = \frac{8}{n\pi}## for even n. The probabilities of measuring energy eigenvalues are determined by ##|c_{n}|^{2}##, and the expectation value of the inverse energy is discussed with a focus on correcting misconceptions regarding time dependency.

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  • Understanding of quantum mechanics principles, particularly wave functions and potential wells.
  • Familiarity with eigenfunctions and eigenvalues in quantum systems.
  • Knowledge of Fourier series expansion techniques.
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  • Learn about the normalization of wave functions and the significance of coefficients in quantum states.
  • Research the implications of measuring energy eigenvalues and their associated probabilities in quantum systems.
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Students and self-learners in quantum mechanics, physicists analyzing potential wells, and educators seeking to clarify concepts related to wave functions and energy measurements.

Irishdoug
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Homework Statement
I'm self studying so I just want to ensure my answers are correct so I know I truly understand the material as it's easy to trick yourself in thinking you do!

A particle of mass m is in a 1-D infinite potential well of width a given by the potential:

V= ##\sqrt{4]/{a}## for 0 ##\leq## x ##\leq## a/4
= ##\infty## elsewhere
Relevant Equations
See below.
I'm self studying so I just want to ensure my answers are correct so I know I truly understand the material as it's easy to trick yourself in thinking you do!

A particle of mass m is in a 1-D infinite potential well of width a given by the potential:

V= 0 for 0##\leq## x ##\leq## a
= ##\infty## for x<a ; x>a

The particle is located in the leftmost quarter of the well at time t = 0 and is described by the wave-function:

##\Psi (x, t=0)## = ##\sqrt{\frac{4}{a}}## for 0 ##\leq## x ##\leq## a/4
= 0 elsewhere

The eigen-functions and eigen-energies are given by ##\phi##(x) = ##\sqrt{\frac{2}{a}}## sin(##\frac{n\pi x}{a}##) and ##E_{n}## = ##{{\hbar}^2 {\pi}^2 {n}^2}/{2m {a}^2}##

Q.1 Write the expansion of the wavefunction ##\Psi ##(x,0) in terms of the eigenfunctions and explicitly compute the expansion co-efficients ##c_{n}##

##\Psi##(x,0) = ##\sum_{n=1}^{\infty} c_{n} \phi_{n}## = ##c_{1} \sqrt{\frac{2}{a}}## sin(##\frac{\pi x}{a}##) + ##c_{2} \sqrt{\frac{2}{a}}## sin(##\frac{2 \pi x}{a}##)... etc.

##c_{n}## = ##\int_{0}^{a/4} \sqrt{\frac{2}{a}} sin( \frac{n\pi x}{a}) \Psi (x,0)dx ##

##\rightarrow## ##\sqrt{\frac{2}{a}} \sqrt{{4}/{a}}## ##\int_{0}^{a/4} sin( \frac{n\pi x}{a}) dx ##

##\rightarrow## -##\frac{8}{a} ( \frac{a}{n \pi} cos (\frac{n\pi x}{a}##))

##\rightarrow## carry out substitution for x

##\rightarrow## -##\frac{8}{n\pi}( cos (\frac{n\pi}{4})) - 1##

so; ##c_{n}## = ##\frac{8-4\sqrt{2}}{n\pi }## for n = odd ; ##\frac{8}{n\pi }## for n = even

Q.2 Give an expression for ##\Psi##(x,t) for some later arbitrary time t

##\Psi##(x,t) = ##c_{n}## ##\phi_{n}(x)## ##exp(\frac{-i Ent}{\hbar})## = ##c_{n}## ## \sqrt{\frac{2}{a}}## ## sin( \frac{n\pi x}{a}) ## ##exp(\frac{-i Ent}{\hbar}##)

Q.3 If an energy measurement is made, what values will be observed and with what probabilities?

I said multiples of ##E_{0}## i.e ##n^{2}## ##(\frac{{\hbar}^2 {\pi}^2}{2m {a}^2}##) where n= 1, 2, 3 etc.

I'm not sure if this is correct. The probabilities are then given by ##|c_{n}|^{2}##

Q.4. What is the probability of measuring ##E_{2}##?

##{|c_{2}|^2}## = ##{\frac{-8}{2\pi}}^2## ##({cos\frac{2\pi}{4} -1})^2##

##\rightarrow## (##{\frac{-8}{2\pi}})^2##(##{-1}^2##) = ##\frac{16}{\pi \pi}##

Q.5 Are there energy egenvalues that will never be observed?

In theory, all eigenvalues can be observed, however in reality some will not as there is not enough time to make measurements to observe all eigen-values.

**I presume this is incorrect but I am unsure how to answer it**

Q.6 Give an expression for the expectation value of the inverse energy ##<\frac{1}{E}>## as a function of time.

##\int_{0}^{a/4} \phi^{*} E \phi dx##

##\frac{\hbar^{2}}{2m}## ##\frac{\partial^2 sin(\frac{n \pi x}{a} )exp(\frac{iEt}{\hbar})}{\partial x^2}##

= ##\frac{\hbar^{2}}{2m}## (-##\frac{a}{n \pi}^{2} ##) ##sin(\frac{n \pi x}{a} )exp(\frac{-iEt}{\hbar})##

so, -##\frac{4 \hbar^{2}}{2m n^{2} \pi^{2}}## ##\int_{0}^{a/4}## ## sin(\frac{n \pi x}{a} )exp(\frac{iEt}{\hbar}) ## ##sin(\frac{n \pi x}{a} )exp(\frac{-iEt}{\hbar})## dxThe exponentials cancel are left with:

-##\frac{4 \hbar^{2}}{2m n^{2} \pi^{2}}## ##\int_{0}^{a/4}## ## sin^{2}(\frac{n \pi x}{a} )##

= -##\frac{4 \hbar^{2}}{2m n^{2} \pi^{2}}## (##\frac{ -2a sin(\frac{n\pi}{2}) - \pi an}{8\pi n}##)

= +##\frac{4 \hbar^{2}}{2m n^{2} \pi^{2}}## (##\frac{ 2a sin(\frac{n\pi}{2}) - \pi an}{8\pi n}##)

You then put this over 1 to get the answer.

I believe this is incorrect however as I have no time dependency! Can someone point out where I have gone wrong. Thankyou.
 
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I think you need to find ##<1/E>## whereas you have found ##<E>##. You can use following:
$$<E^{-1}>= \sum_n|c_n ^2| E_n ^{-1}$$
 
What I did was find <E>, and then I put this over 1. My answer should read:

##\frac{2mn^{2}\pi^{2}}{4\hbar^{2}} \frac{8 \pi n}{2a sin(\frac{n\pi}{2}) - \pi n}##

Is this method incorrect?
 
Irishdoug said:
What I did was find <E>, and then I put this over 1. My answer should read:

##\frac{2mn^{2}\pi^{2}}{4\hbar^{2}} \frac{8 \pi n}{2a sin(\frac{n\pi}{2}) - \pi n}##

Is this method incorrect?
Yes, it's incorrect. E.g. the average of ##1,3## is ##2##. But the average of ##1, 1/3## is not ##1/2##.
 
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