Quantum particle's state in momentum eigenfunctions basis

Click For Summary
SUMMARY

The quantum state of a spinless particle is represented as a point in the Hilbert space of equivalence classes of square-integrable functions, specifically ##L^2## functions defined on ##\mathbb R^3##. The discussion highlights the challenge posed by momentum eigenfunctions, which are not square-integrable, leading to the necessity of advanced concepts such as rigged Hilbert spaces and Gelfand triples for proper treatment. The Lebesgue integral's finiteness is crucial, as it determines the measurability of functions in this context. Hall's book, "Quantum Theory for Mathematicians," provides a rigorous analysis of these concepts.

PREREQUISITES
  • Understanding of Hilbert spaces and equivalence classes of functions
  • Familiarity with Lebesgue integrals and sigma-algebras
  • Knowledge of momentum operators in quantum mechanics
  • Basic concepts of rigged Hilbert spaces and Gelfand triples
NEXT STEPS
  • Study the concept of rigged Hilbert spaces in detail
  • Explore Gelfand triples and their applications in quantum mechanics
  • Read Hall's "Quantum Theory for Mathematicians," focusing on section 3.3
  • Investigate the implications of non-square-integrable functions in quantum mechanics
USEFUL FOR

Quantum physicists, mathematicians specializing in quantum mechanics, and students seeking to deepen their understanding of quantum states and their mathematical foundations.

cianfa72
Messages
2,941
Reaction score
308
TL;DR
How to express quantum particle's state in momentum eigenfunctions basis considering the fact that momentum eigenfunctions are not square-integrable
Hi, as discussed in this recent thread, for a particle without spin the quantum state of the particle is described by a "point" in the Hilbert space of the (equivalence classes) of ##L^2## square-integrable functions ##|{\psi} \rangle## defined on ##\mathbb R^3##.

The square-integrable condition for complex-valued function ##f## means that its square ##|f|^2## has finite Lebesgue integral on the measurable space ##(\mathbb R^3, \mathcal A)## where ##\mathcal A## is the sigma-algebra of Lebesgue measurable sets (or perhaps simply the Borel sigma algebra ##\mathcal B(\mathbb R^3)##).

That said, consider the eigenfunctions ##|{\psi_k} \rangle## of momentum operator ##\vec{P}##. Now the Lebesgue integral of each of their equivalence classes is not finite.

How do we cope with this ? Thanks.
 
Last edited:
Physics news on Phys.org
  • Like
Likes   Reactions: jbergman and PeroK
cianfa72 said:
The square-integrable condition for complex-valued function ##f## means that its square ##|f|^2## has finite Lebesgue integral on the measurable space ##(\mathbb R^3, \mathcal A)## where ##\mathcal A## is the sigma-algebra of Lebesgue measurable sets (or perhaps simply the Borel sigma algebra ##\mathcal B(\mathbb R^3)##).
From a theoretical point of view which type of sigma-algebra is implicitly implied (Borel or Lebesgue) ?
 
Lebesgue on the domain and Borel on the image i.e. the functions are measurable functions ##f: (\mathbb R^3, \mathcal L) \rightarrow (\mathbb C, \mathcal B)##.
 
martinbn said:
Lebesgue on the domain and Borel on the image i.e. the functions are measurable functions ##f: (\mathbb R^3, \mathcal L) \rightarrow (\mathbb C, \mathcal B)##.
Actually not ##f## itself but complex-valued functions ##f## such that the square ##g=|f|^2## is a measurable function ##g: (\mathbb R^3, \mathcal L) \rightarrow (\mathbb C, \mathcal B)##
 
cianfa72 said:
Actually not ##f## itself but complex-valued functions ##f## such that the square ##g=|f|^2## is a measurable function ##g: (\mathbb R^3, \mathcal L) \rightarrow (\mathbb C, \mathcal B)##
It is the same. Composing a continuous function and a measurable function gives a measurable one.
 
  • Like
Likes   Reactions: PeroK and cianfa72
martinbn said:
It is the same. Composing a continuous function and a measurable function gives a measurable one.
Ah ok, this because the Borel ##\sigma##-algebra on ##\mathbb C## is generated by open sets in ##\mathbb C## and the map ##|\, .|^2 : (\mathbb C, \mathcal B) \rightarrow (\mathbb C, \mathcal B)## is continuous (i.e. the preimage of borel sets are borel sets as well).
 
  • Like
Likes   Reactions: martinbn
What about a particle with spin (like the qbit) ? Its quantum state is defined by a point in the projective Hilbert abstract space of dimension 2.

Does exist in this case the concept of wave function, hence the requirement to work with ##L^2## square-integrable functions ?

Edit: perhaps the point is that the Hilbert space for a spin ##1/2## particle is (or it is isomorphic to) the ##\mathbb C^2## Hilbert space (actually the projective line). Hence it is complete under the norm derivated from the standard inner product in ##\mathbb C^2##.
 
Last edited:
cianfa72 said:
TL;DR Summary: How to express quantum particle's state in momentum eigenfunctions basis considering the fact that momentum eigenfunctions are not square-integrable

Hi, as discussed in this recent thread, for a particle without spin the quantum state of the particle is described by a "point" in the Hilbert space of the (equivalence classes) of ##L^2## square-integrable functions ##|{\psi} \rangle## defined on ##\mathbb R^3##.

The square-integrable condition for complex-valued function ##f## means that its square ##|f|^2## has finite Lebesgue integral on the measurable space ##(\mathbb R^3, \mathcal A)## where ##\mathcal A## is the sigma-algebra of Lebesgue measurable sets (or perhaps simply the Borel sigma algebra ##\mathcal B(\mathbb R^3)##).

That said, consider the eigenfunctions ##|{\psi_k} \rangle## of momentum operator ##\vec{P}##. Now the Lebesgue integral of each of their equivalence classes is not finite.

How do we cope with this ? Thanks.
Hall's book Quantum Theory for Mathematicians has the most rigorous analysis of this I have seen if you are really interested.
 
  • Like
Likes   Reactions: martinbn
  • #10
In the Hall's book section 3.3 he claims that ##X\psi(x) = x\psi(x)## might fail to be in ##L^2(\mathbb R)##.

However we know that the function ##x## is continuous and ##\psi(x)## is integrable (w.r.t. the Lebesgue integral over the Lebesgue ##\sigma##-algebra over ##\mathbb R##) by hypothesis. Hence ##x\psi(x)## is measurable too.

Perhaps the point is that we know the above Lebesgue integral exists, however we can not say for sure that it is bounded (not ##+\infty##), right?
 
  • #11
Is the equality in your first paragraph an equation, or a definition of operator action?
 
  • #12
dextercioby said:
Is the equality in your first paragraph an equation, or a definition of operator action?
It is a definition (it defines how the operator ##X## acts on state/vector ##\psi(x)##).
 
  • #13
cianfa72 said:
In the Hall's book section 3.3 he claims that ##X\psi(x) = x\psi(x)## might fail to be in ##L^2(\mathbb R)##.

However we know that the function ##x## is continuous and ##\psi(x)## is integrable (w.r.t. the Lebesgue integral over the Lebesgue ##\sigma##-algebra over ##\mathbb R##) by hypothesis. Hence ##x\psi(x)## is measurable too.

Perhaps the point is that we know the above Lebesgue integral exists, however we can not say for sure that it is bounded (not ##+\infty##), right?
Yes, integrable means finite integral. For example ##\frac1{x^2}## is integrable, but when multiplied by ##x## gives you a non integrable one.
 
  • Like
Likes   Reactions: mattt and cianfa72
  • #14
martinbn said:
Yes, integrable means finite integral. For example ##\frac1{x^2}## is integrable, but when multiplied by ##x## gives you a non integrable one.
I was thinking about what happens at infinity. My example isnt great. One should change the function around zero.
 
  • #15
cianfa72 said:
In the Hall's book section 3.3 he claims that ##X\psi(x) = x\psi(x)## might fail to be in ##L^2(\mathbb R)##.

However we know that the function ##x## is continuous and ##\psi(x)## is integrable (w.r.t. the Lebesgue integral over the Lebesgue ##\sigma##-algebra over ##\mathbb R##) by hypothesis. Hence ##x\psi(x)## is measurable too.

Perhaps the point is that we know the above Lebesgue integral exists, however we can not say for sure that it is bounded (not ##+\infty##), right?
##\psi \in L^2(\mathbb R) \rightarrow \int |\psi(x)|^2dx < \infty##. Hall's statement is merely that there exists ##\psi \in L^2(\mathbb R)## such that ##\int |x\psi(x)|^2dx## is not bounded.
 
  • Like
Likes   Reactions: cianfa72
  • #16
Suppose one deal with a quantum system with position/momentum and spin not entangled. Then the state of system is in the form $$\ket{\psi} \otimes \ket{\chi}$$ and this is a unit vector in the Hilbert tensor product space (i.e. it has norm 1). It follows that the norms of ##\ket{\psi}## and ##\ket{\chi}## considered separately are such that their product is 1, right?
 
  • #17
cianfa72 said:
Suppose one deal with a quantum system with position/momentum and spin not entangled. Then the state of system is in the form $$\ket{\psi} \otimes \ket{\chi}$$ and this is a unit vector in the Hilbert tensor product space (i.e. it has norm 1). It follows that the norms of ##\ket{\psi}## and ##\ket{\chi}## considered separately are such that their product is 1, right?
That's my understanding, yes.
 

Similar threads

  • · Replies 61 ·
3
Replies
61
Views
5K
  • · Replies 29 ·
Replies
29
Views
2K
  • · Replies 1 ·
Replies
1
Views
1K
  • · Replies 0 ·
Replies
0
Views
1K
  • · Replies 35 ·
2
Replies
35
Views
3K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 2 ·
Replies
2
Views
1K
  • · Replies 11 ·
Replies
11
Views
2K
  • · Replies 7 ·
Replies
7
Views
2K
  • · Replies 11 ·
Replies
11
Views
2K