Rates, whats wrong with my working?

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The discussion revolves around calculating the rate constant, k, for the conversion of cyclopropane to propene using first-order kinetics. The user initially calculates k as 0.011576 but finds the textbook answer to be 9.19 x 10^-4. Participants question the units of the provided answer and suggest the possibility of an error in the textbook. The conversation highlights the importance of verifying the reliability of the source material when discrepancies arise. Ultimately, the accuracy of the textbook's answer remains in doubt.
geffman1
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hey guys I've got a question.

We examine the conversion of cyclopropane to propene, a first order process. If we begin with 0.0200 M cyclopropane and find that after 168 s the concentration of propene is 0.00286 M, what is the rate constant, k, at this temperature?

My working:
In[A]-In[A]=-kt
(In0.00286-In0.0200)/168=-k
therefor k=0.011576 however correct answer is 9.19x10-4

anyhelp would be good. thanks
 
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Hello there,

I get the same answer in mol/(L x s) as you. Could you verify that the correct answer is given in the same units?

Thanks.
 
C. 9.19 x 10-4/s here's the answer out exercise, maybe they just made a mistake, are we using the right formula? thanks for the reply
 
You're welcome.

Unfortunately, I still have not found a different answer. Is this textbook a recognised, leading one in chemistry? If not, then the answer key may be erroneous.
 

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