Rates, whats wrong with my working?

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SUMMARY

The discussion focuses on calculating the rate constant, k, for the conversion of cyclopropane to propene, a first-order reaction. The user initially calculated k as 0.011576, while the correct answer is 9.19 x 10-4 s-1. The discrepancy raises questions about the accuracy of the textbook answer key and the formula used for the calculation. Participants confirm that the units for k should be consistent, specifically in mol/(L x s).

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geffman1
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hey guys I've got a question.

We examine the conversion of cyclopropane to propene, a first order process. If we begin with 0.0200 M cyclopropane and find that after 168 s the concentration of propene is 0.00286 M, what is the rate constant, k, at this temperature?

My working:
In[A]-In[A]=-kt
(In0.00286-In0.0200)/168=-k
therefor k=0.011576 however correct answer is 9.19x10-4

anyhelp would be good. thanks
 
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Hello there,

I get the same answer in mol/(L x s) as you. Could you verify that the correct answer is given in the same units?

Thanks.
 
C. 9.19 x 10-4/s here's the answer out exercise, maybe they just made a mistake, are we using the right formula? thanks for the reply
 
You're welcome.

Unfortunately, I still have not found a different answer. Is this textbook a recognised, leading one in chemistry? If not, then the answer key may be erroneous.
 

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