RBS Spectrometry Analysis of Si3N4 on Si: SiO2 or SiOxNy?

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Discussion Overview

The discussion centers around the oxidation of a Si3N4 thin film deposited on a silicon substrate, specifically questioning whether the resulting thin film after oxidation would be SiO2 or SiOxNy. The inquiry involves aspects of chemistry and material science, particularly in the context of Rutherford Backscattering (RBS) spectrometry analysis.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant questions whether the oxidation of Si3N4 will lead to the formation of SiO2 or SiOxNy, suggesting that electronegativity may play a role.
  • Another participant seeks clarification on the structure before and after oxidation, emphasizing the need to understand the resulting layers.
  • A later reply asks for more details about the oxidation conditions, including whether it is epitaxial oxidation and the specifics of the sample processing.
  • It is noted that silicon nitride is resistant to oxidation at moderate temperatures, but the oxidation behavior may differ for thin films.
  • One participant mentions that the outcome may depend on the duration of the oxidation process, indicating that the resulting structure could vary based on this factor.
  • There is a suggestion to include a figure to aid in the discussion, although it has not yet been provided.

Areas of Agreement / Disagreement

Participants express uncertainty regarding the specific outcome of the oxidation process, with multiple competing views on whether SiO2 or SiOxNy will form. The discussion remains unresolved as participants seek more information and clarification.

Contextual Notes

Participants highlight the importance of oxidation conditions and the characteristics of the thin film, which may influence the resulting chemical structure. There are unresolved questions about the specifics of the oxidation process and its effects on the material properties.

Who May Find This Useful

Researchers and students interested in material science, particularly those studying thin film deposition, oxidation processes, and spectrometry analysis in semiconductor applications.

physicist888
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hi all
its an RBS ( rutherford back scattering) experiment. a Si3N4 thin film deposit on a Si substrat. we make a spectrometry analysis, and we obtain the scattering yield spectrum.
now back to chemistry, if we made an oxydation for this thin film while it deposite on the substrat, we'r going to obtain a new thin film of: SiO2 or SiOxNy ? and why?

i can't really solve this question. its really a chemistry question, maybe its about electronegativity of elements.
 
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the new thin film obtained ( SiOxNy or SiO2 ) is deposite on the previous thin film Si3N4.
to be clear, before oxydation : Si/ Si3N4
after oxydation: Si/Si3N4/SiO2 or Si/Si3N4/SioxNy ?? and for which reason??
 
none know about this?
 
What are the conditions during oxidation? We need you to describe the oxidation process in more detail. Is this epitaxial oxidation on a previously grown nitride film? Also, we need a more complete description of the sample and its processing.

Silicon nitride, in general is pretty resistant to oxidation up to moderate temperatures. Above many hundreds of degrees C, the primary mode of oxidation is grain boundary diffusion. Of course, this doesn't apply to thin films.
 
actually, we have first Si/Si3N4 ( substrat/thin film) . then the Si3N4 is deposed under a oxygen flux ( Epitaxial). then a new structure will shown, and that's depends for the duration of oxydation. the question is wer're going to obtain which of the two structures mentioned below??
 
maybe I am going to scan the figure and depose it. is that possible to put figures in the forum??
 
Yes, it is possible. Click the "Go Advanced" option below the Quick Reply box, then click on "Manage Attachments" found below the Reply window (under Additional Options).
 
okay, i didnt scan it yet. tomorrow ill post it
 

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