Reaction of alkaline earth metals with O 2

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Discussion Overview

The discussion revolves around the reactivity of alkaline earth metals with oxygen, specifically focusing on the differences in behavior between magnesium (Mg), beryllium (Be), and heavier alkaline earth metals like barium (Ba), calcium (Ca), and strontium (Sr). The context includes both theoretical aspects of chemical reactivity and practical implications regarding storage and handling of these metals.

Discussion Character

  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • Some participants note that Ba, Ca, and Sr are stored in paraffin due to their high reactivity with oxygen, while Mg and Be can be exposed to air because they form a protective oxide layer.
  • Others argue that the reactivity of alkaline earth metals increases down the group in the periodic table, with Be and Mg being less reactive compared to their heavier counterparts.
  • A participant questions the role of the oxide layer on Mg and Be, suggesting it prevents further reactions, including with acids.
  • Another participant reiterates that the oxide layer formed on Mg and Be is nonreactive and serves to protect the underlying metal from further oxidation.

Areas of Agreement / Disagreement

Participants express differing views on the protective nature of the oxide layer on Mg and Be, with some emphasizing its role in preventing further reactions, while others focus on the general reactivity trends of alkaline earth metals. The discussion remains unresolved regarding the implications of these observations.

Contextual Notes

There are limitations in the discussion regarding the specifics of the oxide layer's properties and the conditions under which these metals react with oxygen and acids. The assumptions about reactivity and protective coatings are not fully explored.

anigeo
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reaction of alkaline Earth metals with O2

i just got in my textbook that Ba,Ca,Sr is kept in paraffin but Mg and Be are not as they form a protective coat of oxide on their surface.i don't get a clue about this .could anyone explain me this?
 
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I don't understand what you don't understand - alkaline metals differ, the lower you are in the periodic table, the more reactive they are. Be and Mg are mildly reactive, they can be kept in contact with the air, those below react violently with the air oxygen, so they are kept submerged in an inert liquid.
 


Borek said:
I don't understand what you don't understand - alkaline metals differ, the lower you are in the periodic table, the more reactive they are. Be and Mg are mildly reactive, they can be kept in contact with the air, those below react violently with the air oxygen, so they are kept submerged in an inert liquid.

what about the coat of oxide on the surface of Mg and Be that prevents them from being attacked by acids.
 


anigeo said:
what about the coat of oxide on the surface of Mg and Be that prevents them from being attacked by acids.

Again, I don't understand what you don't understand and I can only repeat, almost word for word, what you wrote. Fresh surface of the Mg and Be reacts quickly with the air oxygen. Produced oxides stick strongly to the surface and are relatively nonreactive, thus they isolate bulk metal below from the further reactions.
 

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