Saha equation (experiment verification?)

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Discussion Overview

The discussion revolves around the Saha equation and its implications for understanding the ionization fraction of baryonic matter during the recombination era in cosmology. Participants explore theoretical and experimental aspects of the equation, its application to hydrogen and helium, and the conditions of the early universe.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Conceptual clarification

Main Points Raised

  • One participant presents the Saha equation and discusses its application to calculate the fractional ionization X for hydrogen and helium at the current temperature of the universe.
  • Another participant questions whether the current fractional ionization can be derived from the Saha equation, emphasizing the need for thermal equilibrium.
  • Some participants propose two hypotheses regarding the composition of baryonic matter during recombination: one dominated by helium and the other by hydrogen.
  • It is suggested that the ratio of hydrogen to helium today is similar to that during recombination, which could help verify the hypotheses based on current measurements.
  • Discussion arises about the implications of a higher helium density during recombination on the transparency of the universe to photons and the temperature of the cosmic microwave background (CMB).
  • Participants explore the relationship between the timing of recombination, the density of baryonic matter, and the observed temperature of the CMB.
  • There is a debate about whether the CMB would appear hotter or cooler if recombination occurred earlier with a different baryonic composition.
  • One participant raises a question about the trapping of photons in primordial plasma, considering the implications of the η parameter and the interaction rates between photons and baryonic matter.
  • Another participant clarifies that the presence of plasma everywhere would prevent photons from escaping, regardless of their number.

Areas of Agreement / Disagreement

Participants express differing views on the implications of the Saha equation and the conditions of the early universe, particularly regarding the composition of baryonic matter and the effects on the CMB. The discussion remains unresolved with multiple competing views present.

Contextual Notes

Some assumptions regarding thermal equilibrium and the density of baryonic matter are not fully explored, and there are unresolved questions about the interaction rates of photons in the primordial plasma.

ChrisVer
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Hi,
The Saha equation for a procedure a^+ + e \leftrightarrow a + \gamma is:
\frac{1-X}{X^2} = \eta \frac{g_a}{g_{a+}g_e} \frac{4\sqrt{2} \zeta (3)}{\sqrt{\pi}} \Big( \frac{T}{m_e} \Big)^{3/2} \exp \Big[ \frac{E_{binding}(a)}{T} \Big]

where X = \frac{n_{a+}}{n_B} and \eta = \frac{n_B}{n_\gamma}

I worked with this equation for \eta = 5.5 \times 10^{-10} and for a=H and a=^4He. The results I got for \frac{1-X}{X^2} are given the figure picture.
3.jpg

The above Helium line was taken by the assumption that baryonic matter consists only out of Helium at recombination time...

From the log(2) we can see the recombination temperature for both these cases.

I have one question though. Today the temperature is T \approx 2.725~K. So the above line today is going to give me the fractional ionization X for today, right? Is it possible to calculate this fraction though experimentally?
If not, what are the experimental informations you can take from such a diagram?
Also without knowing the value today, how can people determine either the recombination temperature or the fraction of \eta = n_B/n_\gamma?
 
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ChrisVer said:
So the above line today is going to give me the fractional ionization X X for today, right?
Only if the universe is in thermal equilibrium. Do you expect this?
ChrisVer said:
If not, what are the experimental informations you can take from such a diagram?
The ionization fraction in the early universe.
ChrisVer said:
Also without knowing the value today, how can people determine either the recombination temperature or the fraction of ##\eta = n_B/n_\gamma##?
You have the densities now and can extrapolate that backwards to the early universe.
 
So suppose that there are two hypothesis and you want to check them:
1. the baryon number during recombination consisted mainly of He
2. The baryon number during recombination consisted mainly of H
By the plot above, and measurements you can do today, can you verify either the Hyp#1 or Hyp#2?
 
The ratio H/He today is nearly the same as during recombination, so it is easy to get that ratio.
To see which type was type did recombination later (=what produced the CMB), you can look at the plot in post 1.
 
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So in fact, if baryonic number consisted mainly of Helium, the universe would have been transparent to the photons at higher temperatures (=earlier) and thus the radiation temperature from CMB would have been larger today? :)

What I am trying to see is in this:
http://www.helsinki.fi/~hkurkisu/cosmology/Cosmo6.pdf
page 71 in his numbering (or 11 in scrolling)
lowest paragraph
where he states that 90% should have been protons (hydrogen) and the rest Helium..
 
The temperature at the (last) recombination would have been higher, but it would have happened earlier, so the universe would still have had time to cool down afterwards. I guess it would depend on the details like the actual helium density (do you convert all hydrogen to helium, or do you just remove hydrogen?).

ChrisVer said:
where he states that 90% should have been protons (hydrogen) and the rest Helium..
Yes, that's still what we see. 90% hydrogen atoms and 10% helium atoms correspond to roughly 75% hydrogen by mass.
 
The one plot [for Hydrogen] was taken by considering what they state in the link I sent: there was no Helium (Helium neglected)...
The second plot [for Helium] was taken by considering again that there was only Helium (nothing else consisted the baryonic number).
So I guess I what I did was to remove the Hydrogen in the calculations.
I may also be wrong by trying to figure anything out of that graph...

mfb said:
The temperature at the (last) recombination would have been higher, but it would have happened earlier, so the universe would still have had time to cool down afterwards.

But if the universe became transparent at the recombination time, and that is the time we see in CMB, if it had became earlier we would see its "earlier" stage and not the later one (which occurred at Hydrogen). And so it would appear hotter.
 
Hmm, those assumptions will influence η. You also get some inequality between number of helium atoms and number of electrons.
ChrisVer said:
But if the universe became transparent at the recombination time, and that is the time we see in CMB, if it had became earlier we would see its "earlier" stage and not the later one (which occurred at Hydrogen).
Right.
ChrisVer said:
And so it would appear hotter.
Why? It would have cooled down more. There is no reason to assume it would appear hotter.
 
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mfb said:
Why? It would have cooled down more. There is no reason to assume it would appear hotter.

Oh yes, you are right... so CMB would appear cooler.
 
  • #10
Why cooler?

I'm not sure if it would change anything at all. The thermal energy was dominated by photons anyway, the recombination just changed that number by a tiny amount.
 
  • #11
hmm I guess I haven't really understood the mechanisms of temperature evolution then. But I think I solved my problem with it and you are right...the photon temperature almost always (with some small changes) scaled as 1/R even if CMB was produced by He or by H...

I have one further question, if you are able to help...
If the photons were too many combared to baryons and matter, as the \eta parameter tells us, then why were they trapped into the primodial plasma? I know that plasma works as a trap or perfect reflector (by Compton or Ionization) for photons, but is that the case even if the photon number is over-dominating all the rest constituents?
The \eta \sim 10^{-9} means that to 1 proton you have 1 billion photons... and the number of electrons=number of protons (neutrality) so to 1 proton and 1 electron you have 500 million photons... would all the 500million photons interact with these 2 particles in such a rate that they would get trapped? [or an expression for the interaction rate]
 
Last edited:
  • #12
What do you mean with trapped? There was plasma everywhere, how could you escape something that is everywhere?
 

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