Selection rules for multiphoton vs single-photon ionization

Join the discussion
Ask a follow-up here, or get your own question answered by working scientists, mathematicians and engineers — people, not an autocomplete.
Real named experts · corrections over time · the nuance an AI answer skips
2 replies · 2K views
phys-student-9
Messages
2
Reaction score
0
Question: For ionization of a homonuclear diatomic, how do the selection rules differ for a nonresonant 2-photon ionization process and a 1-photon ionization process?
 
Physics news on Phys.org
Specifically, I am wondering about the angular momentum selection rules. For a 1-photon ionization, since the photon has 1 quantum of angular momentum, I think the change in the total orbital angular momentum of the molecule would have to be +/- 1. And for a 2-photon ionization, which I'm trying to do non-resonantly, it would be +/- 2.
The gerade/ungerade selection rules should not matter since these are being ionized.
Does this seem reasonable?