Self-adjoint operators and Hermitian operators are often used interchangeably in finite-dimensional spaces, where both refer to operators that equal their adjoint. In a complex Hilbert space, an operator is self-adjoint if it equals its adjoint, while a Hermitian operator is defined by the property that its conjugate transpose equals itself. The distinction becomes significant in infinite-dimensional spaces, particularly with unbounded operators, where self-adjoint operators have the same domain as their adjoint, while symmetric operators do not necessarily share this property. The spectral theorem applies strictly to self-adjoint operators, making them essential for quantum mechanics, as they represent observables. Understanding these differences is crucial for accurately applying concepts in quantum mechanics and functional analysis.