Sig Figs in Chemistry: Calculate Mass of O2 from Gasoline

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Discussion Overview

The discussion revolves around the application of significant figures (sig figs) in a multi-step chemistry problem involving the calculation of the mass of oxygen required for the complete combustion of gasoline, specifically octane. Participants explore when and how to apply sig figs throughout the calculation process.

Discussion Character

  • Homework-related
  • Mathematical reasoning

Main Points Raised

  • One participant expresses uncertainty about when to apply sig figs in a multi-step calculation, questioning if they should start applying them from the first step.
  • Another participant suggests that all calculations should be done using full precision, with the final results rounded to match the significant figures of the initial value.
  • A participant seeks clarification on whether the initial value of 500.0 g dictates the number of sig figs required throughout the entire calculation.
  • It is noted that while the initial value is critical, other numbers like molar masses are typically known with higher accuracy and may not influence the sig fig requirement in the same way.
  • A later reply acknowledges the helpfulness of the provided guidance on sig figs.

Areas of Agreement / Disagreement

Participants generally agree that the initial value of 500.0 g influences the sig figs throughout the calculation. However, there is some discussion about the treatment of other numerical values, indicating a nuanced understanding rather than a complete consensus.

Contextual Notes

Participants do not fully resolve the implications of using different levels of precision for various constants, such as molar masses, which may affect the overall accuracy of the results.

Who May Find This Useful

Students and individuals working on chemistry problems involving stoichiometry and significant figures may find this discussion relevant.

ilii
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Homework Statement


Calculate what mass of oxygen is required to completely combust 500.0g of gasoline. Assume that the gasoline contains only octane.[/B]

Homework Equations



My problem is... I don't know WHEN to apply sig figs. If this is a multi-step problem (i to iv in this case), do I apply sig figs starting in i)? if I do, then all of my future answers will be influenced by using sig figs early on. When I get to iv) I don't know if all my digits are OK or if they're all way off. Can someone please clean the sig figs up a bit and tell me when I need to apply them? thank you!

The Attempt at a Solution


i) 2C(8)H(18) +25O(2) = 16CO(2) +18H(2)O

ii) 500.0g/114.22852 = 4.377 mol of C(8)H18)

iii) z=4.377 *25/2
z=54.71488206 mol
z=55 mol of O(2)

iv) m(O(2))=55mol*31.9988g/mol
m(O(2))=1759.934 g[/B]
m(O(2))=1760 g
 
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Do all calculations using full precision. Just the numbers you report should be rounded down.

As the initial value has 4 sigfigs, all your results should be reported to 4 sigfigs as well (hence 54.71 moles of oxygen, and not 55 moles).
 
ok, so you're saying that the initial 500.0 stems down through the entire series of steps to the question and 4 sig figs will always be required?
 
Last edited:
As it is the only number here - yes.

(That is - there are other numbers, like molar masses, but we typically know them with much higher accuracy).
 
ok thank you very helpful!
 

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