What Volume of NaOH is Required for Back Titration in Simple Back Titration?

  • Thread starter Thread starter Krushnaraj Pandya
  • Start date Start date
  • Tags Tags
    Titration
Click For Summary
SUMMARY

The forum discussion addresses the calculation of NaOH volume required for back titration after the precipitation of AgCl from a reaction between decinormal HCl and AgNO3. It is established that 10 ml of HCl remains unreacted after the initial reaction, necessitating 10 ml of NaOH for neutralization if only HCl is considered. However, if the formation of HNO3 is taken into account, the required volume of NaOH increases to 20 ml. The discussion emphasizes the importance of neutralizing all H+ ions to accurately determine the amount of Ag+ present.

PREREQUISITES
  • Understanding of back titration principles
  • Knowledge of stoichiometry in acid-base reactions
  • Familiarity with decinormal solutions
  • Basic concepts of precipitation reactions
NEXT STEPS
  • Study the principles of back titration in analytical chemistry
  • Learn about stoichiometric calculations in acid-base reactions
  • Explore the effects of different acids and bases in titration processes
  • Investigate the role of precipitates in titration analysis
USEFUL FOR

Chemistry students, laboratory technicians, and anyone involved in analytical chemistry or titration methods will benefit from this discussion.

Krushnaraj Pandya
Gold Member
Messages
697
Reaction score
73

Homework Statement


20 ml of decinormal HCl soln. is added to 10 ml decinormal AgNO3 soln. AgCl is precipitated out and excess of acid was back titrated against a decinormal NaOH soln., What volume of NaOH was required for the back titration?

2. The attempt at a solution
10 ml HCl reacts with 10 ml AgNO3. 10 ml HCl is left. Now Do we consider HNO3 formed also, since then it'd require 20 ml NaOH. If we consider only HCl it'd be 10
 
Last edited:
Physics news on Phys.org
It hardly counts as a back titration, you are perfectly right that all H+ present initially have to be neutralized (which means there is no way of checking how much Ag+ was present).
 
Borek said:
It hardly counts as a back titration, you are perfectly right that all H+ present initially have to be neutralized (which means there is no way of checking how much Ag+ was present).
Ah! alright, thank you
 

Similar threads

  • · Replies 2 ·
Replies
2
Views
1K
  • · Replies 1 ·
Replies
1
Views
3K
  • · Replies 5 ·
Replies
5
Views
2K
  • · Replies 4 ·
Replies
4
Views
2K
Replies
7
Views
5K
  • · Replies 3 ·
Replies
3
Views
3K
  • · Replies 1 ·
Replies
1
Views
3K
Replies
3
Views
4K
  • · Replies 2 ·
Replies
2
Views
22K
  • · Replies 2 ·
Replies
2
Views
4K