Sol'n of Schrodinger's Eq: A e^{kx-wt} & A Sin(kx-wt)

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The discussion centers on the solutions to Schrödinger's equation, specifically the forms \(\Psi = A e^{kx-wt}\) and \(\Psi = A \sin(kx-wt)\). The exponential solution is confirmed to satisfy the equation, while the sinusoidal solution requires specific conditions to be valid, particularly a "funky potential." The importance of using complex phase factors in wave functions is emphasized, as it preserves linear total energy during differentiation. The conversation highlights the necessity of understanding time-dependent solutions in quantum mechanics.

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The general solution of Schrödinger's equation is givrn by --------
\Psi= A e^{kx-wt}.
And this satisfies the equation .

But the general solution of 3-D sinosidal wave is given by
Psi= A Sin(kx-wt)
And this also satisfies the Schrödinger's equation.

Schrödinger is credited to find the solution as complex phase factor (to signify matter waves) .

Now the question is what is the need of depicting matter waves as complex phase factor ?
 
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I think it has to do with keeping the total energy linear while taking a second derivative. For example: (d2/dt2)(exp[iEt]) = -E^2exp[iEt]. Where as i(d/dt)(exp[iEt]) = -E(exp[iEt]).

In a complex wave equation (i) acts as a derivative because it changes the phase by the same amount (90 degrees) while preserving linear total energy in the solution.
 
zodas said:
The general solution of Schrödinger's equation is givrn by --------
\Psi= A e^{kx-wt}.
And this satisfies the equation .
You're missing an "i" in that argument of the exponential.

But the general solution of 3-D sinosidal wave is given by
Psi= A Sin(kx-wt)
And this also satisfies the Schrödinger's equation.
No it doesn't. Not without some funky potential.
 
LostConjugate said:

Where is the time dependence of the wavefunction? It is not covered in that link. The point is that for an eigenstate of a quantum system, the time-dependent phase is always complex. So it is the "omega-t" term in the sine function mentioned by the OP that makes it not a solution of the TDSE. Try plugging that sine function into the TDSE and see what you get ... you will find that, as bapowell said, it requires a "funky" potential.
 
Got it.
 
Thanks guys !
 

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