Solving Schrodinger's Equation with a weak Imaginary Potential

Click For Summary
SUMMARY

The discussion focuses on solving Schrödinger's Equation with a weak imaginary potential, specifically -iV where V << E. The wavefunction \(\Psi(x,t)\) is derived using the time-independent Schrödinger equation, leading to the characteristic equation involving complex coefficients. The solution reveals that the real part \(a\) and imaginary part \(b\) of the wavefunction are determined through a quadratic equation, ultimately yielding expressions for \(a\) and \(b\) in terms of energy \(E\) and potential \(V\). The probability current density is calculated, illustrating the impact of the imaginary potential on the wavefunction's behavior.

PREREQUISITES
  • Understanding of the time-independent Schrödinger equation
  • Familiarity with complex numbers and their application in quantum mechanics
  • Knowledge of Taylor series approximations
  • Basic principles of quantum mechanics, particularly wavefunctions and probability current density
NEXT STEPS
  • Study the implications of imaginary potentials in quantum mechanics
  • Learn about the derivation and application of the time-independent Schrödinger equation
  • Explore advanced techniques for solving differential equations in quantum contexts
  • Investigate the significance of probability current density in quantum systems
USEFUL FOR

Students and professionals in quantum mechanics, particularly those studying advanced topics in wavefunctions and potential theory. This discussion is beneficial for upper-division undergraduate physics students and researchers focusing on quantum dynamics.

AspiringResearcher
Messages
18
Reaction score
0

Homework Statement


A particle of energy E moves in one dimension in a constant imaginary potential -iV where V &lt;&lt; E.

a) Find the particle's wavefunction \Psi(x,t) approximating to leading non-vanishing order in the small quantity \frac{V}{E} &lt;&lt; 1.

b) Calculate the probability current density of the wavefunction you just calculated, and interpret your result briefly: what is the effect of the small imaginary potential?

Homework Equations


-\frac{\hbar^2}{2m}\psi&#039;&#039; -iV\psi = E\psi \text{ (time-independent Schrödinger equation for energy E)}
j = Re(\bar{\Psi}\frac{\hbar}{im}\frac{d\Psi}{dx})\text{ (probability current density)}

First order approximations for x &lt;&lt; 1:
  • \sin(x) \approx 1
  • \cos(x) \approx 1 - \frac{x^2}{2}
  • e^x \approx 1 + x

The Attempt at a Solution



I attempted this problem in a few different ways and it was never obvious to me how the Taylor approximation would work out.

Since the particle is traveling with a definite energy E, the use of the time-independent Schrödinger equation is justified. The time dependence is easy to calculate.

The first approach I used was to solve the time-independent Schrödinger equation with the standard method for second-order homogeneous linear differential equations with constant coefficients. I modified this approach by assuming that the coefficient r in \psi = e^{rx} would be complex, setting r = a + bi for simplicity.

Assume \psi(x) = e^{(a+bi)x}.

The characteristic equation is then
-\frac{\hbar^2}{2m}(a+bi)^2 = E + iV
which leads to the equations
a^2 -b^2 = \frac{-2mE}{\hbar^2} \text{ for the real part}
2abi = -\frac{2miV}{\hbar^2} \text{ for the imaginary part}
Therefore, ab = -\frac{mV}{\hbar^2} \implies b = -\frac{mV}{a\hbar^2}
\implies a^2 - b^2 = a^2 - \frac{m^2V^2}{a^2\hbar^4} = -\frac{2mE}{\hbar^2}
\implies a^4 + \frac{2mE}{\hbar^2}a^2 - \frac{m^2V^2}{\hbar^4} = 0
Using the quadratic formula,
a^2 = \frac{-\frac{2mE}{\hbar^2}\pm \sqrt{\frac{4m^2E^2}{\hbar^4}+\frac{4m^2V^2}{\hbar^4}}}{2}
Since a must be a real number, the solution with the subtraction will not work, so we have
a^2 = -\frac{mE}{\hbar^2} + \frac{m}{\hbar^2}\sqrt{E^2+V^2} = \frac{m}{\hbar^2}(\sqrt{E^2+V^2}-E)
Now, taking the square root, I assume that a will be negative or else \psi will be non-normalizable and will blow up, so we have
a = -\frac{\sqrt{m}}{\hbar}\sqrt{\sqrt{E^2+V^2}-E}
Substituting this value for a into the formula for b, we obtain
b = \frac{\sqrt{m}V}{\hbar\sqrt{\sqrt{E^2+V^2}-E}}

I do not know how to proceed from here on out. Clearly the \frac{\sqrt{m}}{\hbar} term can be factored out in the exponential, but I cannot see how Taylor approximation for e^{(a+bi)x} would lead to vanishing terms.

In my other attempt, I tried a solution \psi(x) = f(x)\phi(x) for some function f(x), where \phi is just the wavefunction for a free particle with definite energy E. However, this was not enlightening.

EDIT: I posted this in the "Advanced Physics Homework" section because I did not feel it was appropriate for the introductory homework section. This is from an upper-division undergraduate QM class.
 
Last edited:
Physics news on Phys.org
You might have neglected some higher order terms already by using the time-independent Schroedinger equation. You can neglect more to simplify the expression for a and b.

What is ##\sqrt{E^2+V^2}## approximately for V<<E?
 

Similar threads

  • · Replies 2 ·
Replies
2
Views
3K
Replies
2
Views
2K
Replies
5
Views
2K
Replies
29
Views
2K
Replies
1
Views
2K
Replies
14
Views
3K
  • · Replies 20 ·
Replies
20
Views
3K
Replies
7
Views
2K
Replies
1
Views
2K
Replies
7
Views
3K