Some questions on energy of orbitals

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The discussion centers on the degeneracy of orbitals, specifically the px, py, and pz orbitals in the electronic configuration 0=[He] 2s² 2px² 2py¹ 2pz¹. It is established that while px, py, and pz are generally degenerate, the presence of electrons can affect their stability and energy levels. The inert pair effect is addressed, with participants seeking clarification on its underlying reasons. Additionally, the order of the shielding effect is confirmed as s > p > d > f, indicating the relative effectiveness of these orbitals in shielding nuclear charge.

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1. We know px,py,pz are degenerate orbitals... My question is suppose in
0=[He] 2s^2 2px^2 2py^1 2pz^1
Are the px,py,pz orbitals degenerate here?

2. What is the true reason of inert pair effect?

3. What is the order of shielding effect for s,p,d,f?I just want to verify my answers...
 
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Ezio3.1415 said:
1. We know px,py,pz are degenerate orbitals... My question is suppose in
0=[He] 2s^2 2px^2 2py^1 2pz^1
Are the px,py,pz orbitals degenerate here?

2. What is the true reason of inert pair effect?

3. What is the order of shielding effect for s,p,d,f?


I just want to verify my answers...

Please show your work and your answers.
 
1. the orbitals were degenerate... Now px is more stable,means less energy... so py and pz are degenerate...

2. I know about it... Was expecting an answer and justify whether the things I read are true...

3. s>p>d>f
my ques is why?
 

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