Spin in Real Space: Meaning of Z-Component

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SUMMARY

The discussion centers on the concept of spin in quantum mechanics, specifically addressing the z-component of spin and its relationship to real space. It is established that while spin degrees of freedom are independent of configuration space, spin operators are connected to real space directions. The intrinsic nature of spin is emphasized, distinguishing it from classical angular momentum and highlighting its role as an additional degree of freedom that combines with orbital angular momentum to form total angular momentum.

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  • Familiarity with the Schrödinger equation and wave functions.
  • Knowledge of spinor representations and Pauli matrices.
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TL;DR
The project of spin on real space
If the spin space is independent of the real space, what is the meaning of, for example, the z-component of the spin?
 
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hokhani said:
Summary:: The project of spin on real space

If the spin space is independent of the real space, what is the meaning of, for example, the z-component of the spin?
The z-component of spin is a measurable quantity. The abstract spin vectors describe the spin state, but the spin operators represent real observables.
 
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hokhani said:
the spin space is independent of the real space

It isn't. The spin degrees of freedom are independent of the configuration space (position and momentum) degrees of freedom. But the spin operators are still connected to directions in real space.
 
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PeterDonis said:
It isn't. The spin degrees of freedom are independent of the configuration space (position and momentum) degrees of freedom. But the spin operators are still connected to directions in real space.
Do you mean that there is something of real-rotation entity in spins?
 
In quantum mechanics spin is a contribution to the total angular momentum not related to the orbital angular momentum you are familiar with from classical mechanics, where it is ##\vec{L}=\vec{r} \times \vec{p}##.

The problem is that we have not a real intuition for the quantum world, so we have to use some more abstract thinking to get an intuition about it. Spin is most easily introduced as a field-theoretical concept, because then you have at least some intuition from classical field theory (though the only classical field theory except fluid dynamics, where you only deal with orbitarl angular momentum, is electromagnetism, and there you deal with a massless relativistic vector field, where the notion of spin is not as for massive fields, and there's no non-relativistic limit for it).

To get an idea, how to introduce angular momentum in a field theory we consider simply wave mechanics a la Schrödinger as a classical field theory though there is no classical physical interpretation to the Schrödinger wave function. To define what's angular momentum we have to remember that in classical mechanics (Hamilton formalism) angular momentum is the quantity that is conserved due to invariance under rotations (isotropy of Galilean spacetime) and thus angular momentum is the generator of rotations.

So let's start with the usual scalar Schrödinger field, ##\psi(t,\vec{x})##. Consider an infinitesimal rotation of the spatial coordinates, ##\vec{x}'=\vec{x}+\delta \vec{\varphi} \times \vec{x}##, where ##\delta \vec{\varphi}## is an infinitesimal vector pointing in the direction of the rotation axis and ##\delta \varphi=|\delta \vec{\varphi}|## is the infinitesimal rotation angle. Now since the Schrödinger field is a scalar field it transforms as
$$\psi'(t,\vec{x}')=\psi(t,\vec{x})=\psi(t,\vec{x}'-\delta \vec{\varphi} \times \vec{x}) = \psi(t,\vec{x}') - (\delta \vec{\varphi} \times \vec{x}) \cdot \vec{\nabla}' \psi(t,\vec{x}').$$
The infinitesimal change of the field thus is
$$\delta \psi(t,\vec{x})=-\delta \vec{\varphi} \cdot (\vec{x} \times \vec{\nabla}) \psi(t,\vec{x}).$$
Since (using units with ##\hbar=1## for simplicity)
$$\hat{\vec{p}}=-\mathrm{i} \vec{\nabla}$$
you can write this is
$$\delta \psi(t,\vec{x})= -\mathrm{i} \delta \vec{\varphi} \cdot (\vec{x} \times \hat{\vec{p}}) \psi(t,\vec{x}).$$
Since (total) angular momentum generates by definition rotations you should have
$$\delta \psi(t,\vec{x})=-\mathrm{i} \delta \vec{\varphi} \cdot \hat{\vec{J}} \psi(t,\vec{x}).$$
Since this is true for any ##\delta \vec{\varphi}## this implies that for the usual scalar Schrödinger field
$$\hat{\vec{J}} = \hat{\vec{x}} \times \hat{\vec{p}}=\hat{\vec{L}},$$
i.e., for this case the total angular momentum is just the (quantized) familiar orbital angular momentum of classical mechanics.

However, there are more possibilities for a field theory. In quantum mechanics it turns out that from the commutation relations for angular momenta you can get some kind of angular momentum not familiar from classical physics, namely socalled spinor representations with half-integer spin quantum number. The most simple is spin 1/2, describing, e.g., an electron. In non-relativistic physics this spin is independent of ##\hat{\vec{x}}## and ##\hat{\vec{p}}## and thus you have a fourth independent variable which usually is chosen as ##\hat{s}_3=\frac{1}{2} \sigma_3## with the Pauli matrix ##\sigma_3=\mathrm{diag}(1,-1)##. Then the wave functions get (Weyl-)spinor valued, i.e., the wave function has two components ##\psi_{\sigma}(t,\vec{x})## with ##\sigma \in \{1/2,-1/2 \}##, and we write the wave function as a column vector,
$$\psi(t,\vec{x})=\begin{pmatrix} \psi_{1/2}(t,\vec{x}) \\ \psi_{-1/2}(t,\vec{x}) \end{pmatrix}.$$
As it turns out, the infinitesimal rotation of such an object is defined as
$$\psi'(t,\vec{x}')=(1- \mathrm{i} \delta \vec{\varphi} \cdot \hat{\vec{s}} \cdot \psi(t,\vec{x}'-\delta \vec{\varphi} \times \vec{x}').$$
The same calculation as above, neglecting all contributions with ##\delta \varphi^2## (linear approximation), you get
$$\delta \psi(t,\vec{x}) = -\mathrm{i} \delta \vec{\varphi} \cdot (\hat{\vec{L}}+\hat{\vec{s}}) \psi(t,\vec{x}),$$
which leads to
$$\hat{\vec{J}}=\hat{\vec{L}} + \hat{\vec{s}}.$$
So the spin is an additional intrinsic contribution to the angular momentum of the particle, independent of its orbital motion.
 
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hokhani said:
Do you mean that there is something of real-rotation entity in spins?

No. I meant what I said. Read it again.
 
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The spin must not be somehow visualized as some "mechanical rotation of something", but it's an intrinsic angular momentum of a particle. Physically, at least for a charged particle, it implies a magnetic moment, but it can have any gyrofactor ##g## and not ##1## as predicted by classical physics or as for the magnetic moment associated with orbital angular momentum in quantum mechanics.
 
I tend to just avoid the idea that spin is connected to something rotating and think of it more in terms of an extra degree of freedom such that it combines with the orbital angular momentum, (L+S) to give a conserved quantity, whereas neither are conserved independently. If you try to imagine spin as being something rotating in any classical sense, you end up with some really weird notion of spinning that doesn't relate to anything you would actually see rotating. For example, to rotate the electron spin from some "starting orientation" back to that same orientation requires "turning it around" by 720 degrees, not 360. It's best to just think of spin as a relativistic effect that gives you an additional degree of freedom which lacks a classical counterpart.
 
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