Stirling's approximation/Multiplicity

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SUMMARY

The forum discussion focuses on using Stirling's approximation to analyze the multiplicity function of a large two-state paramagnet. The peak height in the multiplicity function is determined to be \(2^N\) when \(N_{\uparrow} = N/2\). The derived formula for the multiplicity function in the vicinity of the peak is \(\Omega = N^N[(N/2+x)(N/2-x)]^{-N/2}(\frac{N/2-x}{N/2+x})^x\), which aligns with the peak height when \(x = 0\). The discussion highlights the importance of Taylor series expansion and neglecting higher-order terms for large \(N\) to accurately describe the width of the peak.

PREREQUISITES
  • Understanding of Stirling's approximation: ln(N!) = N ln(N) - N
  • Familiarity with multiplicity functions in statistical mechanics
  • Knowledge of Taylor series expansions
  • Basic concepts of two-state systems in thermodynamics
NEXT STEPS
  • Study the implications of Stirling's approximation in statistical mechanics
  • Learn about Gaussian distributions and their relevance to multiplicity functions
  • Explore the derivation of microstate counts in statistical ensembles
  • Investigate the behavior of two-state systems under varying conditions
USEFUL FOR

This discussion is beneficial for physics students, particularly those studying statistical mechanics, as well as researchers working on thermodynamic systems involving two-state particles.

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Homework Statement


For a single large two-state paramagnet, the multiplicity function is very sharply peaked about N_{\uparrow} = N/2

a) Use Stirling's approximation to estimate the height of the peak in the multiplicity function.

b) Use the methods in this section to derive a formula for the multiplicity function in the vicinity of the peak, in terms of x \equiv N_{\uparrow} - (N/2) Check that your formula agrees with your answer to part (a) when x = 0.

c) How wide is the peak in the multiplicity function?

Homework Equations



Stirling's approximation: ln(N!) = N ln(N) - N

# of microstates = \frac{N!}{N_{\uparrow}!N_{\downarrow}!}

The Attempt at a Solution



The first question seems simple enough; I'll just plug in N/2:
ln \Omega = ln(N!) - ln((N/2)!) - ln((N/2)!)
ln \Omega \approx Nln(N) - N - 2((N/2)ln(N/2)-N/2) = Nln(N)-Nln(N/2) = Nln(2)

So the answer to (a) is 2^N. This seems problematic though because I think 2^N should be the total number of microstates for all macrostates, not just the macrostate where half the dipoles are "up"...Do I need to include the \sqrt{2{\pi}N} term in Stirling's approximation?

For (b), I managed to get the formula:
\Omega = N^N[(N/2+x)(N/2-x)]^{-N/2}(\frac{N/2-x}{N/2+x})^x
which does give me 2^N where x=0, but I expected to get a gaussian curve, especially considering part (c). But I can't see how I can get an exponential in the final answer because the exponentials seem to cancel out whether or not the square root term is in there.

What am I missing here? Am I on the right track at all?
 
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So it turns out this is fairly involved but not too complicated. All that's required is using the Taylor series expansion for the natural logarithm and neglecting terms because x<<N (since N is large and the question asks for the behavior "in the vicinity" of the peak)
 

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