Tensor products and simultaneous eigenstates

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SUMMARY

The discussion centers on the representation of simultaneous eigenstates in quantum mechanics, particularly in the context of angular momentum operators as described in Townsend's "A Modern Approach to Quantum Mechanics." The participants analyze the expression for eigenstates of hydrogen-like systems, specifically the relationship between the radial and angular components of the wave function. They conclude that while one can express the state as a tensor product, care must be taken regarding the notation and the definitions of the eigenstates involved. The radial part of the wave function is dependent on the quantum number l, which is a critical point in understanding the overall state representation.

PREREQUISITES
  • Understanding of quantum mechanics concepts, particularly angular momentum.
  • Familiarity with Dirac notation and tensor products in quantum states.
  • Knowledge of spherical harmonics and their role in quantum mechanics.
  • Basic principles of eigenstates and eigenvalues in Hermitian operators.
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  • Study the derivation and properties of spherical harmonics in quantum mechanics.
  • Explore the implications of tensor products in quantum state representation.
  • Learn about the radial Schrödinger equation and its dependence on quantum numbers.
  • Investigate the definitions and properties of Hermitian operators in quantum mechanics.
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Quantum mechanics students, physicists specializing in quantum theory, and researchers interested in the mathematical foundations of quantum states and their representations.

LightPhoton
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In A Modern Approach to Quantum Mechanics, Townsend writes:



One of the most evident features of the position-space representations (9.117), (9.127), and (9.128) of the angular momentum operators is that they depend only on the angles ##\theta## and ##\phi##, not at all on the magnitude ##r## of the position vector. Rotating a position eigenstate changes its direction but not its length. Thus we can isolate the angular dependence and determine ##\langle \theta, \phi | \ell, m \rangle##, the amplitude for a state of definite angular momentum to be at the angles ##\theta## and ##\phi##. These amplitudes, which are functions of the angles, are called the spherical harmonics and denoted by

$$\langle \theta, \phi | \ell, m \rangle = Y_{\ell, m}(\theta, \phi) \tag{9.132}$$

where

$$\hat L_z\rightarrow\frac\hbar i\frac\partial{\partial
\phi}\tag{9.117}$$ $$\hat L_x\rightarrow\frac\hbar
i\bigg(-\sin\phi\frac\partial{\partial\theta}-\cot\theta\cos\phi\frac\partial{\partial\phi}\bigg)\tag{9.127}$$
$$\hat L_y\rightarrow\frac\hbar
i\bigg(\cos\phi\frac\partial{\partial\theta}-\cot\theta\sin\phi\frac\partial{\partial\phi}\bigg)\tag{9.128}$$


Then he states that since an eigenstate of a hydrogen-like system can be written as ##\vert E,l,m\rangle##, we have


$$\langle r,\theta,\phi\vert E,l,m\rangle=R(r)Y_{\ell, m}(\theta, \phi)$$



Does this mean that he means one could write ##\vert E,l,m\rangle= \vert E\rangle\otimes\vert l,m\rangle## and ##\langle r,\theta,\phi\vert=\langle r\vert\otimes\langle\theta,\phi\vert##?


If yes, then does this mean that when we say we have a simultaneous eigenstate of three variables ##\vert x,y, z\rangle##, what we really mean is that we have a state ##\vert x\rangle\otimes\vert y\rangle\otimes\vert z\rangle##?
 
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LightPhoton said:
Then he states that since an eigenstate of a hydrogen-like system can be written as ##\vert E,l,m\rangle##, we have
$$\langle r,\theta,\phi\vert E,l,m\rangle=R(r)Y_{\ell, m}(\theta, \phi)$$
This expression is wrong, because the radial part ##R_l(r)## of the wave function depends on the quantum number ##l## (but it does not depend on ##m##). This is because after the separation of variables the "leftover" one-dimensional radial Schrödinger equation still contains a term ##\propto l(l+1)##.

LightPhoton said:
Does this mean that he means one could write ##\vert E,l,m\rangle= \vert E\rangle\otimes\vert l,m\rangle## and ##\langle r,\theta,\phi\vert=\langle r\vert\otimes\langle\theta,\phi\vert##?
This depends on what the symbols ##|r \rangle## and ##|\theta, \phi \rangle## mean. Are they the eigenvectors of Hermitian operators? If so, what are those operators and what are the associated eigenvalues? Further, if one can apparently write ##|r, \theta, \phi \rangle = |r \rangle \otimes |\theta, \phi \rangle##, then can one also write ##|\theta, \phi \rangle = |\theta \rangle \otimes |\phi \rangle##?

The point is, if you solve a given problem and thus know the correct steps leading to the solution already, then you can introduce any arbitrary form of (Dirac) notation and then present your reasoning to other people using this notation - but then you risk others not understanding you. Does this textbook's author defines what they mean by the expression ##|r, \theta, \phi \rangle## somewhere in the text?

LightPhoton said:
(...) when we say we have a simultaneous eigenstate of three variables ##\vert x,y, z\rangle##, what we really mean is that we have a state ##\vert x\rangle\otimes\vert y\rangle\otimes\vert z\rangle##?
Yes - but see my above comment on notation. For example, is it true that ##\vert x\rangle\otimes\vert y\rangle\otimes\vert z\rangle = \vert y\rangle\otimes\vert x\rangle\otimes\vert z\rangle##?
 

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