The birth of statistical mechanics

Click For Summary
SUMMARY

The discussion centers on the historical development of statistical mechanics, highlighting the early contributions of Ludwig Boltzmann and James Clerk Maxwell. Boltzmann's 1877 paper introduced concepts of energy as a continuous parameter, while Maxwell's work led to the Maxwell-Boltzmann distribution. The conversation also touches on the influence of quantum mechanics on statistical mechanics, particularly regarding energy quantization and the Gibbs paradox. Key references include Boltzmann's original paper and sections from Tobochnik and Gould's work.

PREREQUISITES
  • Understanding of statistical mechanics principles
  • Familiarity with quantum mechanics concepts
  • Knowledge of classical mechanics and energy distribution
  • Awareness of historical figures in physics, particularly Boltzmann and Maxwell
NEXT STEPS
  • Research Boltzmann's 1877 paper on statistical mechanics
  • Study the Maxwell-Boltzmann distribution in detail
  • Explore the Gibbs paradox and its implications in classical and quantum mechanics
  • Investigate modern treatments of classical statistical mechanics, particularly in relation to quantum mechanics
USEFUL FOR

Students and researchers in physics, particularly those interested in the historical context of statistical mechanics, quantum mechanics, and energy distribution theories.

ShayanJ
Science Advisor
Insights Author
Messages
2,802
Reaction score
605
This topic is about history of physics so I decided to post it in general physics section but it would be nice to have a history of physics(or maybe science)section.
Anyway,during my statistical mechanics course,I realized QM is being used from the beginning,in contrast to other parts of physics where a classical theory is developed first and then there are quantum corrections.So I wondered whether there was a time that there was classical statistical mechanics.I know,you now tell "of course there was" but by classical statistical mechanics I mean not considering energy levels and degeneracies and considering energy as a continuous parameter.
I found Boltzmann's 1877 paper at http://www.trivialanomaly.com/ and took a look at it.In it,boltzmann assumes that particles can take velocities of the form \frac{p}{q} and also he assumes that the energy(he uses the term "alive force" which I think he means energy)of any particle is an integer multiple of a constant factor.
Also in http://arxiv.org/pdf/physics/9710007.pdf , it is said that Max Planck was inspired by Boltzmann's ideas in his theory about black body radiation.
We know that maxwell independently had discovered maxwell-boltzmann distribution.I want to know had maxwell also have the idea of energy quantization or he just derived the distribution experimentally?
Also I will appreciate any ideas about classical statistical mechanics and whether there is a distribution which considers energy as a continuous parameter.
Thanks
 
Physics news on Phys.org
Yes, there is a "classical statistical mechanics" in which energy is considered as a continuous parameter - or, more precisely, energy is a function of the continuous state variables of position and momentum. However, it turns out that in order to write down sensible densities of states, etc., you need to bin the positions and momentum. The bin widths ##\Delta x## and ##\Delta p## end up entering into the density of states as the product ##\Delta x \Delta p##, so modern treatments tend to use our knowledge of quantum mechanics to identify this bin area with ##\hbar## (raised to the appropriate power if in 2 or 3 dimensions).

See, for example, sections 3.6 and 4.3.2 of Tobochnik and Gould, available online here: http://stp.clarku.edu/notes/
 
Yeah,my thoughts also led me to the result that classically,a particle has infinite number of choices for its energy content.So I concluded that for finding a classical energy distribution,a different approach should be taken.
Maybe we can tell that every energy between 0 and E is equally probable and probability distribution is 1/E.
 
Statistical mechanics - Wikipedia, the free encyclopedia has a short history, mentioning several contributors who lived well before the discovery of quantum mechanics. Contributors like James Clerk Maxwell and Ludwig Boltzmann, who worked half a century before.

ETA:
Gibbs paradox - Wikipedia, the free encyclopedia mentions the problem of what to do about phase space in the classical limit. It also mentions a problem with counting that quantum mechanics successfully resolves. Its discoverer, Josiah Willard Gibbs, Jr., had died in 1903.
 

Similar threads

  • · Replies 6 ·
Replies
6
Views
2K
Replies
4
Views
1K
  • · Replies 1 ·
Replies
1
Views
728
  • · Replies 4 ·
Replies
4
Views
3K
  • · Replies 1 ·
Replies
1
Views
2K
Replies
2
Views
3K
  • · Replies 6 ·
Replies
6
Views
2K
  • · Replies 16 ·
Replies
16
Views
2K
  • · Replies 4 ·
Replies
4
Views
2K
Replies
5
Views
4K