Thermal Physics: 2 Cases, Ratio V(1)/V(2) for Small T

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SUMMARY

The discussion focuses on calculating the ratio V(1)/V(2) for two ideal gases in a cylinder at very low temperatures (T approaching zero). The first case involves both gases being fermions, while the second case features one gas as bosons and the other as fermions. Participants emphasize that the ideal gas law (PV = NkT) is not applicable at low temperatures for quantum gases. Instead, they recommend deriving pressure expressions for both Fermi and Bose gases from first principles to accurately determine the volume ratio.

PREREQUISITES
  • Understanding of quantum gases, specifically Fermi and Bose gases.
  • Familiarity with the Fermi distribution and Bose-Einstein distribution.
  • Knowledge of thermodynamic principles, particularly pressure-volume relationships.
  • Basic concepts of Bose-Einstein condensation and its implications on gas behavior.
NEXT STEPS
  • Derive the pressure expression for Fermi gases at zero temperature.
  • Study the derivation of pressure for Bose gases from first principles.
  • Learn about Bose-Einstein condensation and its effects on particle density.
  • Explore advanced thermodynamic concepts related to ideal quantum gases.
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Students and researchers in thermal physics, physicists specializing in quantum mechanics, and anyone studying the behavior of ideal gases at low temperatures.

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I had a question about 2 cases

we have a cilinder with 2 Ideal Gases. The volume, mass and the number of particles
is given. So We call it V(1),M(1),N(1) for the first gas and V(2),M(2),N(2) for
the second gas. The two gases are separated by a movable wall

Now what is the Ratio V(1)/V(2) for very small T (almost zero) if

1. both gases consist of fermions
2.the first gas consist of bosons and the other one form fermions


I thought for the both cases I use PV=NKT. And so express V in the other quantities.
Then use the fermi distribution and the bose-distribution. But using this I get all kinds of quantities which I don't have.
Can someone help me with this?

thanks for the help
 
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You cannot use PV = NkT for an ideal quantum gas at low temperatures.

In case of the Fermi gas, you know that in the linit of zero temperature, the pressure becomes a nonzero constant. It is given by minus the derivative of the total ground state energy w.r.t. volume.

If you don't exactly remember how this is computed, you should first study this before attempting to solve this problem.

In case of the Bose gas, you know that a macroscopic fraction of the molecules will be in the ground state below the critical temperature for Bose-Einstein condensation. There is a maximum density for the particles that are not in the condensate.

You should first derive an expression for the pressure for the Bose gas from first principles before proceeding with this case.
 

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