There's a dover book called "Statistical Thermodynamics" by Erwin Schrödinger, I have worked through "Concepts in Thermal Physics" by Schroeder and I think Erwin's book blends some of thermodynamics with quantum mechanics so I don't think I'll be able to comprehend it, anyways I just wanted to...
I was going through the textbook Thermodynamics and an Introduction to Thermostatistics by Herbert B. Callen, and in Chapter 2.4 of the book, the author proves that given two subsystems separated by an impermeable and immovable wall which only allows for the transfer of heat, the temperature of...
I was studying the principles of air conditioning and came across some questions. In an air conditioner, the refrigerant absorbs heat while evaporating indoors, thereby lowering the temperature, and releases heat while condensing outdoors, thereby raising the temperature. According to the second...
I made a presentation where I derived, or at least attempted to derive, the formulae for the upper bounds of the efficiency/cop (cop = coefficient of performance) for a heat engine, work driven heat pump, and a heat driven heat pump with 3 thermal reservoirs, hot, warm, and cold. There are many...
At first, I tried to calculate the heat energy required by doing this:
I realized I should calculate heat energy separately instead of grouping glass and water together so I did this:
But the answer is supposed to be 6.29 x 10^4.
I don't know how to solve this. Can anyone help please? Thank you
Hi,
The solution for this question is
thermal energy lost= thermal energy gained
0.200x450x(300-T)=1.0x4200x(T-20)
T=26 degrees celcius.
However, I am struggling to grasp why (300-T) is used.
I have always known a change in something to be final - initial. Therefore change in T= Final-...
By using the given relationship that S=a/T --(1) along with the equation ∫ (delta Q rev)/T=∫dS -- (2) I found out that my answer for the value of Q is mc*ln (T2/T1)*a upon equating (1) & (2).
But the solution is instead given as Q=a*ln*(T1/T2).
I would be grateful if someone would point out...
lambda (rms)= v(rms) * t(rms) -- 1
Now I assume here that t(rms)=1/(√2*n*π*d^2*v(rms))
But this cancels the v(rms) term when used in eq (1) so the mean free path and the RMS free path would actually be the same (even later on when used in the aforementioned Survival Equation)
I would like to...
The question is given in 3 parts.
For first part, process is isochoric so Work done=0. We know here that at end of the process (a), T2=T1 while V remains constant (we can take it as V1) so P2=2P1.
For second part, process is isothermal so T is constant. At end of process we reach P1 again from...
There are two questions in the photo.
I have attempted the solution (attached below) and I would be highly obliged if someone would verify the same.
Edit- Sorry the images of the solution have uploaded in the wrong order. 5th and 1st Image comprise of both parts of Q1 while the remaining of Q2.
For the first part, I have expressed it in the following differential form- dU= delta (Q) + BdM
Now for the second part I am having major confusion. I know that B corresponds to P and M corresponds to V as generalised force and generalised displacement respectively for a Paramagnetic substance...
We have the area of incandescence. Using that we can find the radius and subsequently the diameter.
A=π* r^2 -----> r= 0.0025m so d=0.005m
Using the formula (given by Clausius as we are not specified in question whether it's a Maxwellian distribution or not)
Mean Free Path λ=...
<Using the hint, I tried to find the van der Waal constants in molar form. Since STP is mentioned, I used the unitary method relationship-
22.4 L=22400cm^3=1 molar V
<To find a possible conversion standard between cm^3 and mol; which turned out to be 1cm^3= 4.46*10^-5 mol.
<Then I used the...
Hello folks,
I have a bit of a time sensitive question, if anyone happens to read this soon.
A computer box consumes 80W power constantly. Outside temperature T= 290 Kelvin. Ambient pressure 10^5.
If all the heat generated is expelled at 5 litres per second, estimate the inside...
Summary:: TLDR : Drink cooled from 17 C to 7 C with either ice cubes (method 1) or soapstone stones (method 2). Calculate the mass of each item that would be needed to cool the same drink. Given the information provided.
In order to cool a drink (“cola” for example) from a storage-room...
Consider instead a thermally insulated container of volume V with a
small hole of area A, containing a gas with molecular mass m. At time t = 0, the density is ##n_0## and temperature is ##T_0##. As gas effuses out through a small hole, both density and temperature inside the container will...
Frankly, i don't even know how to start this. I deducted from the solution, that they must have used power/(specific heat capacity x temperautre), however i don't understand how that will give the rate of flow of air. Could anybody help, please?
Hey guys, I have Thermal as a course in this (undergrad) semester and the teacher is very bad. Any book recommendations for me to study entirely on my own? This is what we have to cover in the course:
Disclaimer: I am not a mathematician, I am a physicist.
The thermodynamic identity is usually expressed in the following differential form
$$
dU = TdS - PdV + \mu dN,
$$
where U , T , S , P , V , \mu and N are the internal energy, temperature, entropy, pressure, volume, chemical...
First, I calculated the heat required for the ice to melt:
Q=mLf
Q=0.150×330
Q=49.5 J
Then, I calculated the final temperature of the water by forming the following equation:
Q=mcΔT
−49.5=(0.15+0.35)×4200×(Tf −80)
Tf=80.0 degrees Celcius
But the answer says 32 degrees Celsius.
There is this one problem from past exam papers which I cannot seem to do:
The air in a kitchen has pressure 1.0 x 10^5 Pa and temperature 22'C. A refrigerator of internal volume 0.36 m^3 is installed in the kitchen.
(a) With the door open the air in the refrigerator is initially at the same...
Basic Procedure
The experiment basically involves finding the null point on the Carey Foster's bridge with the PRT as the unknown resistance and using a Resistance box as the variable resistance.
In the above diagram, P and Q are 2 fixed resistors of equal resistances.
For obtaining the first...
## \Omega(E_1)## is the number of microstates accessible to a system when it has an energy ##E_1## and ##\Omega(E_2)## is the number of microstates accessible to the system when it has an energy ##E_2##. I understand that each microstate has equal probability of being occupied, but could...
For a canonical ensemble the probability of occupying a certain microstate varies depending on the energy, however I thought that every microstate has an equal chance of being occupied. So what part of the canonical ensemble have I misunderstood?
Hi all, I have an issue trying to understand the following paragraph from Blundell's book.
How, exactly, does the definition of ##\mu_0 = E_F## "make sense"? In the sentence after 30.21, it seems to say that the mean energy for a system with ##N## particles differs from that of a system with...
Hey guys, so I am reading this book and on pages 89-90, the author says:
"Increasing temperature correspond to a decreasing slope on Entropy vs Energy graph", then a sample graph is provided, and both in that graph and in the numerical analysis given in page 87 the slope is observed to be an...
Hi all, I have been having some issues trying to show that a reversible expansion of gas does not create new entropy. Assistance is greatly appreciated!
So suppose that a gas expands reversibly as shown below at fixed temperature
At fixed temperature, internal energy doesn't change so...
Homework Statement
Hi all, I am having issues with the following problem. Assistance is greatly appreciated!
Homework EquationsThe Attempt at a Solution
a) The "law of mass action" I know of is just the equilibrium constant, which I wrote in terms of partial pressures at equiilbrium
$$K =...
For a reaction defined as such,
$$A\rightleftharpoons B$$
the equilibrium constant ##K## is defined by ##K = p_B / p_A##, with ##p## denoting the partial pressure (edit: at equilibrium). However, if ##K<<1##, which implies ##p_A >> p_B##, it is said that the backwards reaction dominates and that...
Hi all, I have an issue with understanding the following passage in the aforementioned book. I have uploaded the relevant passage as an image below. Any assistance is greatly appreciated!
The paragraph under equation (22.57) says that the total Helmholtz function ##F## is a sum of Helmholtz...
Homework Statement
A metal ball of mass 1kg is heated by means of a 20W heater in a room at 20°C. The temperature of the ball becomes steady at 50°C. (a) Find the rate of loss of heat to the surrounding when the ball is at 50°C. fa) Assuming Newton's law of cooling, calculate the rate of loss...
It's been a while since I studied physics. I did a few basic courses in physics as a freshman, but I never studied any physics since, but instead majored in math and ended up doing a math PhD. Nowadays, I work on self-driving cars at a large tech company, where my work is mostly in computer...
I'm having trouble picturing the energy states for some systems. For instance, I was reading Reif's Fundamentals of Statistical and Thermal Physics, and at some point he talks about the energy states of a pool acting as a heat reservoir interacting with a bottle of wine. The problem is that...
Homework Statement
A steel ring with a hole having area of 3.990 cm2 is to be placed on an aluminum rod with crosssectional area of 4.000 cm2. Both rod and ring are initially at a temperature of 35.0°C. At what common temperature can the steel ring be slipped onto one end of the aluminum rod...
Homework Statement
Star 1 emits energy at a rate that is 2 times that of Star 2. If Star 1 also has a radius that is 3 times larger than Star 2, how do the temperatures of the stars compare?
a. Star 1's temperature is 2.58 that of Star 2.
b. Star 1's temperature is 3.75 that of Star 2.
c...
Homework Statement
The bottom of a circular, aluminum pot has a radius of 8cm and a thickness of 1cm. The temperature of the stove top is 120 degrees celsius and the temperature of the pot initially is 20 degrees celsius. What is the rate at which energy is transferred through the bottom of the...
Homework Statement
How much energy must be removed from the system to turn liquid copper of mass 1.5kg at 1083 degrees celsius to solid copper at 1000 degrees celsius?
a. -2.49X10^5J
b. -3.67X10^4J
c. 2.25X10^3J
d. 9.45X10^4J
e. -2.78X10^3J
Homework Equations
Q=Mc(Tf-Ti)...
Homework Statement
[/B]
I have solve the rest of this problem pretty easily and see no problems with working with Indistinguishable particles, Distinguishable particles, fermions and Bosons. Part c has me very confused though about what it is even asking.
Suppose a system with equally spaced...
Are the following definitions correct?
Work done as energy transferred
The energy transferred when the forces between two objects interact
Work done by a force
Work done = force x distance moved in the direction of force applied (W=F*Δs)
Work done by a gas
Work done = pressure x change...
Homework Statement
What is the kinetic energy of a particle in 2mol of nitrogen gas at atmospheric pressure that is within a volume of 100m^3?a. 1.27X10^-17J
b. 3X10^5J
c. 6.8X10^-16J
d. 2.97X10^7
e. 9.9X10^-14J
Homework Equations
PV=nRT
n=Numberof particles/Na
Na=6.02x10^23
R=8.13 J/Mol
The...
When an ideal gas,in a piston kind of system and whose equilibrium state is mentioned, is allowed to expand (piston is allowed to move and not gas leaking )against a constant external pressure very quickly, then, is the work done by gas zero or not zero ?
The argument for work being zero is...
Hello all.
I am studying Thermal Physics from Schroeder's book. I really like this book, but the number of worked examples and solved problems is minimum. Could you please suggest me a complemetary book with worked examples and problems? The ideal book should be similar to Schroeder's, with the...
Making use of the partition function, it is straight forward to show that the entropy of a single quantum harmonic oscillator is:
$$\sigma_{1} = \frac{\hbar\omega/\tau}{\exp(\hbar\omega/\tau) - 1} - \log[1 - \exp(-\hbar\omega/\tau)]$$However, if we look at the partition function for a single...
Homework Statement
Homework EquationsThe Attempt at a Solution
How to do part ii)?
I differentiate part i with respect to p
(∂H/∂P)T = T (∂S/∂P)T + V ...(1)
Then I used the equation given in the question,
Applying maxwell equation I got
(∂T/∂V)S = -(∂P/∂S)V ...(2)
I planned to substitute...
Homework Statement
Question (b) (iii)
Homework EquationsThe Attempt at a Solution
The energy required to melt the ice is
Q1=mL=3*0.025*3.3*10^5=24750J
The energy released by water is
Q2=mcT=0.33*4200*(22-T)
Shall I calculate the energy that the ice needs after it melts into water?
i.e...
Homework Statement
Homework Equations
##dS = \frac{1}{T} (dU - PdV)## assuming dN = 0
The Attempt at a Solution
I have actually managed to solve all 4 parts correctly, except for the fact that I solved Part d) with the Sackur-Tetrode equation rather than the thermodynamic identity.
I...
Homework Statement
A 1 kg parcel of dry air initially at a temperature of 15 Celsius (288 K) rises from ground level to its equilibrium height, which corresponds to a pressure of 750 hPa.
What is the decrease in internal energy?What is the temperature of the air parcel at its equilibrium...