Time Independent Schrödinger equation.

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Discussion Overview

The discussion revolves around the Time Independent Schrödinger equation and its relationship with time and kinetic energy in quantum mechanics. Participants explore the nature of stationary states, the concept of evolution in time, and the implications of kinetic energy in quantum systems.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • Some participants question why the Time Independent Schrödinger equation incorporates time, given its focus on stationary states.
  • Others argue that in quantum mechanics, a state can possess non-zero kinetic energy while remaining stationary and not evolving in time.
  • A participant seeks clarification on the meaning of "evolve" in this context, suggesting that spatial movement implies a velocity and thus kinetic energy cannot be zero.
  • It is proposed that a particle can exist in a superposition of states, leading to a zero average velocity while still having kinetic energy.
  • Some participants assert that quantum states always evolve in time according to Schrödinger's equation, but the statistical properties of observables can remain constant over time.
  • A later reply questions whether the probabilities associated with quantum states remain unchanged during their evolution.

Areas of Agreement / Disagreement

Participants express differing views on the relationship between kinetic energy, time evolution, and the nature of stationary states in quantum mechanics. There is no consensus on these points, and the discussion remains unresolved.

Contextual Notes

Participants highlight the complexity of defining "evolution" in quantum mechanics and the implications of superposition on kinetic energy and probability distributions. The discussion reflects various interpretations and assumptions about these concepts.

MixedHerbs
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Pardon my ignorance but why does the Time Independent Schrödinger equation use Time?

It uses a kinetic energy operator.

Kinetic energy; "It is defined as the work needed to accelerate a body of a given mass from rest to its stated velocity."

Velocity is;

"The scalar absolute value (magnitude) of velocity is speed, a quantity that is measured in meters per second (m/s or ms−1) when using the SI (metric) system."

Peter.
 
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In quantum mechanics a state can have non-zero kinetic energy and yet still be "stationary" in that it does not evolve in time.

Contrast classical mechanics, where a particle with non-zero kinetic energy is, almost by definition, in motion and so in a time-dependent state.
 
The_Duck said:
In quantum mechanics a state can have non-zero kinetic energy and yet still be "stationary" in that it does not evolve in time.

Contrast classical mechanics, where a particle with non-zero kinetic energy is, almost by definition, in motion and so in a time-dependent state.

May I ask what do you mean by 'evolve' with time? Becuase if you imply it moves spatially with time then you are implying a velocity and hence kinetic energy cannot be zero? Would that be right?

Thanks
 
Quantum mechanically, a particle can be in a superposition of two distinct states. For example, it could be in a superposition of a left-moving state with some speed and a right-moving state with the same speed. Then the "expectation" (average) value of the velocity of the particle is zero. Yet the particle clearly has kinetic energy. Extending this idea you can have states where the particle has kinetic energy, yet the probability of finding it at any given point is independent of time. This is what I mean by "does not evolve in time."
 
The_Duck said:
In quantum mechanics a state can have non-zero kinetic energy and yet still be "stationary" in that it does not evolve in time.

Oh, but quantum states do always evolve in time, as per Schroedinger's equation which is a consequence of a Galilei, Poincare or conformal invariant dynamics.

It's just that one can find systems whose quantum states evolve in time in such a way that the statistics of observables (which can be associated to possible outcomes of measurements) is preserved at all times.
 
Ok guys, Thank you.
 
dextercioby said:
Oh, but quantum states do always evolve in time, as per Schroedinger's equation which is a consequence of a Galilei, Poincare or conformal invariant dynamics.

It's just that one can find systems whose quantum states evolve in time in such a way that the statistics of observables (which can be associated to possible outcomes of measurements) is preserved at all times.

So, for example 70% probability finding a quantum system (say, an atom) in position1, and 30% in position2, as the evolution of the Schrödinger equation occurs, those 70% and 30% probabilities for the applicable positions stay the same?
 

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