Titrating Biodiesel for soap content

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SUMMARY

This discussion focuses on titrating biodiesel for soap content using hydrochloric acid (HCl). The user requires a 0.01N HCl solution and has 38% HCl available. To prepare 1 liter of the desired solution, the correct method involves diluting 0.83 mL of the concentrated 12N HCl into a 1L flask and then adding distilled water to the mark. An alternative method for those unable to measure less than 1 mL is to first dilute 1 mL of strong acid in 5 mL of water and then use 5 mL of that solution in 1 liter of water.

PREREQUISITES
  • Understanding of normality and molarity in solutions
  • Familiarity with titration techniques
  • Knowledge of handling hydrochloric acid safely
  • Basic laboratory skills for measuring liquids accurately
NEXT STEPS
  • Research the properties and uses of bromophenol blue in titrations
  • Learn about the preparation of standard solutions in chemistry
  • Study the principles of acid-base titration
  • Explore safety protocols for handling concentrated acids
USEFUL FOR

Chemistry students, laboratory technicians, and anyone involved in biodiesel production or titration methods will benefit from this discussion.

whatarascal
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Good afternoon people

I wish to titrate biodiesel for soap content.There are video's on you tube describing how.
I have all the bits required including bromophenol blue and hydrochloric acid.
The acid is at 38% and I need a solution of .01N HCl.
Well its a long time since I was at school and even then I may not have been capable of working this out.
I require 1 litre of the .01 solution.
Would one of you bright young sparks tell me how to work this out or better still calculate it for me.
It would be great if I knew the right amount of acid to add to the distilled water.

Thanks a lot in advance
 
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You are talking about making up a 0.01 N solution rather than a 0.0100 N solution so you don't need to be very exact since you only want 1 significant figure for your standard. If that's what you want, dilute the 38% HCL (12 N) by adding 0.83 mL of the concentrated acid to a 1L flask and dilute to the mark. If you can't accurately measure less than 1 mL, first add 1 mL strong acid to 5 mL water and use only 5 ml of the resulting 6 mL of solution in a liter of water.
 

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