Two hydroxides doesn't matter in this problem

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Discussion Overview

The discussion revolves around the calculation of the volume of hydrochloric acid (HCl) required to neutralize a given volume of barium hydroxide (Ba(OH)2), specifically addressing the role of the two hydroxide ions in the reaction and the stoichiometric relationships involved.

Discussion Character

  • Homework-related
  • Mathematical reasoning
  • Debate/contested

Main Points Raised

  • One participant expresses confusion about why the presence of two hydroxides in Ba(OH)2 is considered negligible in the problem.
  • Another participant suggests that the stoichiometric ratio of the reaction should be clarified and emphasizes the need to calculate the number of moles in both substances.
  • A third participant agrees with the initial setup of the calculation, asserting that for each mole of Ba(OH)2, two moles of HCl are indeed required, leading to a calculated volume of 40 mL.
  • A later reply indicates that the original answer provided by the teacher was incorrect, confirming the participant's calculation of 40 mL.

Areas of Agreement / Disagreement

Participants generally disagree on the correctness of the initial answer provided by the teacher, with some supporting the calculation that results in 40 mL while others suggest a different answer of 20 mL without reaching a consensus on the correct interpretation of the stoichiometry.

Contextual Notes

There are unresolved aspects regarding the stoichiometric calculations and the interpretation of the reaction, particularly how the presence of two hydroxides influences the overall neutralization process.

kazimmerman
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I'm having trouble understanding why the fact that there are two hydroxides doesn't matter in this problem.

What volume of 0.150-molar HCl is required to neutralize 25.0 milliliters of 0.120-molar Ba(OH)2?

I thought the setup would look like this simple enough:

(25.0 mL)(.120 M)(2) = (.150 M)(V)

and the volume came out to be 40.0 mL. I assumed that the neutralization reaction looked like this:

2HCl + Ba(OH)2 --> 2H2O + BaCl2

so for each mole of Ba(OH)2 there would be two moles of HCl. However, I was told the answer was 20.0 mL. Why is the presence of two hydroxides negligible, or is the answer I was given incorrect?
 
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First of all, work out the reaction, what is the stoichiometric ratio of this reaction.

Secondly, work out the number of moles in both substances
then it should be basic plugging and chugging.
 
kazimmerman said:
I thought the setup would look like this simple enough:
(25.0 mL)(.120 M)(2) = (.150 M)(V)
I see nothing wrong with this. For each mole of Ba(OH)2 you need
2 moles of HCl to neutralize it. V=40 mL.
 
Thanks for the replies. I had it confirmed with my teacher today and he simply made a mistake when grading the test. ;)
 

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