Understanding Burstein-Moss Shift

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SUMMARY

The Moss-Burstein shift is a phenomenon observed in semiconductors, particularly when doping levels reach a degenerate state. As the doping concentration increases, the Fermi level rises into the conduction band, resulting in an increase in the observed band gap during absorption measurements. This occurs because electrons can only be excited to states above the Fermi level, which is now within the conduction band, leading to the equation: Observed band gap = Actual band gap + Moss-Burstein shift. This effect is significant in understanding semiconductor behavior under high doping conditions.

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i have searched it online but i can't find any material describing this effect. >.<

what is it about?:confused:

thanks for answering:smile:

kit
 
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Hi,

I am new to the forum. And this is my first post.

Moss-Burstein shift:- The effect happens in semiconductors. If you nominally dope the semiconductor (say n-type), the Fermi level lies below the conduction band edge and above the occupied donor states. If you increase the doping more and more, and when you reach a degenerate level of doping, Fermi level moves into the conduction band. The effect becomes more when you increase the donor concentration more. Now, if you try to measure the band gap by absorption measurement, an electron at the top of the valence band can only be excited to a state above the Fermi level (which now lies in the conduction band) because all the states below the Fermi level are occupied donor states. You cannot excite electrons into the occupied states as Pauli's exclusion principle forbids it. Thus what you will observe is increased band gap. ie.,

Observed band gap = Actual band gap + MB shift.

Hope this explains you.

-Jithesh
 
I do not have a good working knowledge of physics yet. I tried to piece this together but after researching this, I couldn’t figure out the correct laws of physics to combine to develop a formula to answer this question. Ex. 1 - A moving object impacts a static object at a constant velocity. Ex. 2 - A moving object impacts a static object at the same velocity but is accelerating at the moment of impact. Assuming the mass of the objects is the same and the velocity at the moment of impact...

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