Using exponents and logarithms to calculute pH

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Diluting a strong acid solution with an equal volume of water results in a change in pH that can be expressed as pH_diluted = pH_original + log 2. The pH is defined as the negative logarithm of hydrogen ion concentration, pH = -log[H+]. Doubling the volume of the solution only slightly alters the pH, as a full unit change requires a tenfold change in concentration. The discussion highlights the importance of correctly applying logarithmic principles in pH calculations. Overall, the dilution leads to a minor pH increase due to the logarithmic relationship with hydrogen ion concentration.
interhacker
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Homework Statement



If a solution containing a heavy concentration of hydrogen ions(i.e., a strong
acid) is diluted with an equal volume of water, by approximately how much is its
pH changed? (Express (pH)diluted in terms of (pH)original.)

Homework Equations



I think the question requires the equation defining pH:
pH = \log[H+]

The Attempt at a Solution



According to the document, the answer is supposed to be:

pH_{dilute} = pH_{original} + \log 2
 
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If the concentration of H+ ions in the original (undiluted) solution is [H+] and you add approximately an equal amount of H+ ions by diluting the original solution, what is the total concentration of H+ ions in the dilute solution?
 
interhacker,
pH means negative of the logarithm of hydrogen ion concentration; you were missing the negative sign.
pH = -log[H+]

If you just double the volume to make the dilution, this is only a fraction of a pH unit change. The concentration change must be up or down by a factor of 10 for a change of pH of one unit.
 
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He must have made another mistake that canceled out the first one and made the answer right! :biggrin:
 

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