Using oxalic acid as a primary standard

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Discussion Overview

The discussion centers on the use of oxalic acid as a primary standard for the standardization of basic solutions, specifically sodium hydroxide. Participants explore the feasibility and methodology of this application, touching on titration processes and indicators used in the reactions.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Mathematical reasoning

Main Points Raised

  • One participant questions whether oxalic acid can be used as a primary standard for standardizing sodium hydroxide, expressing uncertainty about potential limitations.
  • Another participant mentions that oxalic acid is available as a standard solution from a supplier, suggesting its accessibility for use.
  • A participant provides the chemical formula of oxalic acid, contributing to the technical details of the discussion.
  • There is a proposal that the reaction between oxalic acid and sodium hydroxide would be a standard acid-base neutralization, resulting in sodium oxalate and water, with the need for an indicator like phenolphthalein to determine the endpoint of the titration.
  • One participant shares their experience with titrating oxalic acid using potassium permanganate, noting that it acts as a self-indicator.
  • Another participant confirms that oxalic acid can be used in alkalimetry, emphasizing the importance of ensuring it is in the dihydrate form for accurate results.

Areas of Agreement / Disagreement

Participants express varying degrees of confidence regarding the use of oxalic acid as a primary standard for sodium hydroxide. While some affirm its applicability, others raise questions about its limitations, indicating that the discussion remains somewhat unresolved.

Contextual Notes

Participants do not fully address potential limitations or assumptions regarding the use of oxalic acid as a primary standard, such as the need for precise conditions or the implications of its dihydrate form.

danago
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Hi. Can oxalic acid be used as a primary standard to standardise a basic solution, such as sodium hydroxide?

I can't think of any reason why it couldn't be used, but i could very much be missing something.
 
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It is available as a standard solution from Aldrich (Fixanal).
 
What is forumla of oxalic acid?
 
formula of oxalic acid is HOOC-COOH (ethanedicarboxylic acid)
 
Would it just be a standard acid base neutralization reaction, where the acid reacts with a base, such as NaOH, to form a salt, sodium oxalate, plus water. Id need to use an indicator such as phenolphthalein though, to indicate the end point of the titration.
 
yes. I have done titration of oxalic acid with potassium permanganate (KMnO4;it is a self indicator)
 
Sourabh N said:
yes. I have done titration of oxalic acid with potassium permanganate (KMnO4;it is a self indicator)

yea so have i, but i was just wondering if it could be used as a primary standard with a basic solution, such as NaOH. I know it works with KMnO4
 
It works for alkalimetry as well. Just remember to dry it to be sure it is exactly dihydrate.
 
ok that's the answer i was after :) Thanks
 

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