Vinegar Electrolysis: Dark Brown Material + Blue Solution

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Discussion Overview

The discussion revolves around the results of vinegar electrolysis using copper electrodes, specifically focusing on the identification of a blue solution and a dark brown material produced during the process. Participants explore the chemical nature of these substances, including potential compounds formed during electrolysis.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant observed dark brown material on the cathode and a blue solution during vinegar electrolysis with copper electrodes and questioned the identity of these substances.
  • Another participant suggested that the blue solution is likely a copper aqua complex.
  • A participant inquired about the exact nature of the copper aqua complex and whether there is a specific formula for it.
  • A link to a Wikipedia page on metal aquo complexes was provided for further information.
  • One participant expressed curiosity about why the solution is identified as aquo rather than copper acetate or hydroxide, seeking clarification on how to confirm its identity.
  • Another participant noted that hydroxide is a solid and mentioned that copper acetate complexes could form, depending on vinegar concentration and stability constants.
  • There was a question about whether the aquo complex is the same as a colloid, to which a participant clarified that hydroxide is a solid while the aquo complex is a dissolved cation.

Areas of Agreement / Disagreement

Participants have differing views on the identity of the blue solution, with some supporting the idea of it being a copper aqua complex while others raise the possibility of copper acetate or hydroxide. The discussion remains unresolved regarding the exact nature of the compounds formed.

Contextual Notes

Participants acknowledge the dependence on vinegar concentration and complex stability constants, which may influence the formation of different copper compounds. There are also unresolved questions about the definitions and characteristics of the substances discussed.

MadM
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I tried vinegar electrolysis using 2 copper electrodes and 9v adaptor
it gave dark brown material on the (-) electrode
blue solution
what is the blue solution? since i used white vinegar (which contains water) could it be copper hydroxide?or copper acetate?
what is the brown material on the cathode?
 
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Blue is most likely copper aqua complex.
 
? what is this exactly? is there an exact formula of it?
 
Thanks for this infos
But why is it aquo? why not acetate or hydroxide ? how can i make sure it is aquo and not another copper compound??
 
And another thing
Is this aquo the same thing as colloid?
 
Last edited:
MadM said:
But why is it aquo? why not acetate or hydroxide ? how can i make sure it is aquo and not another copper compound??

Hydroxide is a solid. Some copper acetate complex is possible, but how much - depends on the vinegar concentration and complex stability constants.

MadM said:
Is this aquo the same thing as colloid?

No. Hydroxide is a solid, aquo complex is a dissolved cation (whatever the counter ion is).
 
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