Wavefunctions and boundaries of a 1D-potential well

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Homework Help Overview

The discussion revolves around the formulation of wavefunctions for a one-dimensional potential well, specifically focusing on boundary conditions and the continuity of wavefunctions and their derivatives at specified boundaries.

Discussion Character

  • Conceptual clarification, Assumption checking, Mathematical reasoning

Approaches and Questions Raised

  • Participants explore the correct formulation of wavefunctions across different regions of the potential well and question the continuity of these functions and their derivatives at the boundaries. There is a focus on the implications of infinite potential on the wavefunctions.

Discussion Status

Some participants have provided corrections regarding the notation of the wavefunction in certain regions and have suggested that the continuity of the wavefunction and its derivative must be maintained at the boundaries. There is an ongoing exploration of the implications of potential boundaries on the wavefunctions.

Contextual Notes

Participants are discussing the implications of infinite potential on the behavior of wavefunctions at the boundaries, particularly regarding kinetic energy considerations and the physical realism of the wavefunctions in those regions.

indie452
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the attachment here shows a potential well and i am practicing writing down wave functions in each region and boundary conditions (for this problem I suppose the boundaries would be x= -a, 0, b.

i think that for this problem i need 4 functions and i thought that they may be:

when
x<-a (1) = 0
-a<x<0 (2) = Asin(k1x) + Bcos(k1x)
0<x<b (3) = Csin(k2x) + Dcos(k2x)
b>x (4) = 0

where
k1 = ([tex]\sqrt{}2mE[/tex])/[tex]\hbar[/tex]
k2 = ([tex]\sqrt{}2m(E-Vo))/\hbar[/tex]

and i think at the boundary x = -a and b the wave function is continuous and at x=0 the wave function and the first derivative is continuous.

Is this right?
thanks
 

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|.........|
|.........| Vo < E
|.........|
|......__________|
|......|
|......|
|......|
|......|
-a......0....b

V(x)=
infinity --- x<-a --- region 1
0 --- -a<x<0 --- region 2
Vo --- 0<x<b --- region 3
infinity --- b<x --- region 4

if you can't see the pic
 
first thing:

maybe you want to think again about what you stated here when you said "b>x (4) = 0", i believe you have done simple mistake since you wrote the first three equations correctly, it actually should be "x>b (4) = 0"

second thing:

dont you think that you should make your wavefunction continuous by appliying the fact that the wavefunction and its derivative (1st) in region(1) = the wavefunction and its derivative (1st) in region(2) and that when x = -a , and the same goes with region(2) and (3) when x = 0 , also region(3) and (4) when x = b ..

hmm, well .. I think so .. what do you think?
 
for the first thing your right i did write it down wrong t=it was meant to be b<x.

but with the the reason i wrote that the first derivative of the wavefunction is not continuous at the boundary x=-a, and b was cause i thought that when on the otherside of a boundary the potential->infinity, so KE->-infinty at boundaries so first derivative->infinity also. this is cause it seems to be infinite potential and so not physically realistic.
 
for the first thing your right i did write it down wrong t=it was meant to be b<x.

but with the the reason i wrote that the first derivative of the wavefunction is not continuous at the boundary x=-a, and b was cause i thought that when on the otherside of a boundary the potential->infinity, so KE->-infinty at boundaries so first derivative->infinity also. this is cause it seems to be infinite potential and so not physically realistic.
 
thats mainly the reason behind choosing the wavefunction = 0 in both regions 1 and 4..

lets first consider the situation when we say that the wavefunction and its derivative should be continuos in region (1) and (2) when x = -a ..

you have in region (2) that the wavefunction = A sin(k1x) + B cos(k1x) .. so when x = -a

in region(2) the wavefunction = - A sin(k1a) + B cos(k1a) & you know that the wavefunction in region(1) at x = -a is zero >>> then 0 = -A sin(k1a) + B cos(k1a)
im not allowed to proceed more than this, but i think you got the point (I hope!) .. continue with the derivatives .. and don't forget the other regions ..

good luck..
 
for the first thing your right i did write it down wrong t=it was meant to be b<x.

but with the the reason i wrote that the first derivative of the wavefunction is not continuous at the boundary x=-a, and b was cause i thought that when on the otherside of a boundary the potential->infinity, so KE->-infinty at boundaries so first derivative->infinity also. this is cause it seems to be infinite potential and so not physically realistic.
 

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